The Deracemization of Secondary Alcohols via a Chemo-Enzymatic Process
文献类型：期刊论文
| 作者 | Sun W(孙伟) ; Sun W(孙伟); Xia CG(夏春谷)
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| 刊名 | Letters in Organic Chemistry
 |
| 出版日期 | 2008 |
| 卷号 | 5期号:8页码:672-675 |
| 关键词 | Deracemization oxidative agent Rhodotorula sp. AS2.2241 chemo-enzymatic one-pot secondary alcohols |
| ISSN号 | 1570-1786 |
| 通讯作者 | 夏春谷 ; 孙伟 |
| 中文摘要 | Optically pure secondary alcohols were efficiently prepared via a two-step, one-pot process involving a chemical oxidative agent in combination with an enantioselective ketone reducase Rhodotorula sp. AS2.2241 in tandem. The reaction proceeded successfully with 88~99.5% enantiomeric excess in moderate to good conversions. A variety of substrates, including aromatic and aliphatic alcohols, could be tolerated. |
| 学科主题 | 清洁催化与生物转化 |
| 收录类别 | SCI |
| 资助信息 | the NSFC (20625308;20643008);Chinese Academy of Sciences |
| 语种 | 英语 |
| WOS记录号 | WOS:000261926400014 |
| 公开日期 | 2012-12-04 |
| 源URL | [http://210.77.64.217/handle/362003/2355]  |
| 专题 | 兰州化学物理研究所_OSSO国家重点实验室 |
| 通讯作者 | Sun W(孙伟); Sun W(孙伟); Xia CG(夏春谷) |
| 推荐引用方式 GB/T 7714 | Sun W,Sun W,Xia CG. The Deracemization of Secondary Alcohols via a Chemo-Enzymatic Process[J]. Letters in Organic Chemistry,2008,5(8):672-675. |
| APA | 孙伟,孙伟,&夏春谷.(2008).The Deracemization of Secondary Alcohols via a Chemo-Enzymatic Process.Letters in Organic Chemistry,5(8),672-675. |
| MLA | 孙伟,et al."The Deracemization of Secondary Alcohols via a Chemo-Enzymatic Process".Letters in Organic Chemistry 5.8(2008):672-675. |
入库方式： OAI收割
来源：兰州化学物理研究所
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