Organic Ligand-Free Alkylation of Amines, Carboxamides, Sulfonamides,and Ketones by Using Alcohols Catalyzed by Heterogeneous Ag/Mo Oxides
文献类型:期刊论文
作者 | Cui XJ(崔新江)![]() ![]() ![]() ![]() |
刊名 | Chem. Eur. J.
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出版日期 | 2011 |
卷号 | 17页码:1021-1028 |
关键词 | Ag/Mo amines carboxamides ketones sulfonamides |
ISSN号 | 0947-6539 |
通讯作者 | 石峰 |
中文摘要 | Complicated and expensive organic ligands are normally essential in fine chemical synthesis at preparative or industrial levels. The synthesis of fine chemicals by using heterogeneous catalyst systems without additive organic ligand is highly desirable but severely limited due to their poor generality and rigorous reaction conditions. Here, we show the results of carbon–nitrogen or carbon–carbonbond formation catalyzed by an Ag/Mo hybrid material with specific Ag6Mo10O33 crystal structure. 48 nitrogen-or oxygen-containing compounds, that is, amines, carboxamides, sulfonamides, and ketones, were successfully synthesized through a borrowing-hydrogen mechanism. Up to 99% isolated yields were obtained under relatively mild conditions without additive organic ligand. The catalytic process shows promise for the efficient and economic synthesis of amine, carboxamide, sulfonamide, and ketone derivatives because of the simplicity of the system and ease of operation. |
学科主题 | 物理化学 |
收录类别 | SCI |
资助信息 | the “Hundred Talents Program” of the Chinese Academy of Sciences |
语种 | 英语 |
公开日期 | 2012-12-04 |
源URL | [http://210.77.64.217/handle/362003/2378] ![]() |
专题 | 兰州化学物理研究所_绿色化学研究发展中心 |
通讯作者 | Shi F(石峰); Shi F(石峰) |
推荐引用方式 GB/T 7714 | Cui XJ,Shi F,Deng YQ,et al. Organic Ligand-Free Alkylation of Amines, Carboxamides, Sulfonamides,and Ketones by Using Alcohols Catalyzed by Heterogeneous Ag/Mo Oxides[J]. Chem. Eur. J.,2011,17:1021-1028. |
APA | 崔新江,石峰,邓友全,&石峰.(2011).Organic Ligand-Free Alkylation of Amines, Carboxamides, Sulfonamides,and Ketones by Using Alcohols Catalyzed by Heterogeneous Ag/Mo Oxides.Chem. Eur. J.,17,1021-1028. |
MLA | 崔新江,et al."Organic Ligand-Free Alkylation of Amines, Carboxamides, Sulfonamides,and Ketones by Using Alcohols Catalyzed by Heterogeneous Ag/Mo Oxides".Chem. Eur. J. 17(2011):1021-1028. |
入库方式: OAI收割
来源:兰州化学物理研究所
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