中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Organic Ligand-Free Alkylation of Amines, Carboxamides, Sulfonamides,and Ketones by Using Alcohols Catalyzed by Heterogeneous Ag/Mo Oxides

文献类型:期刊论文

作者Cui XJ(崔新江); Shi F(石峰); Deng YQ(邓友全); Shi F(石峰)
刊名Chem. Eur. J.
出版日期2011
卷号17页码:1021-1028
关键词Ag/Mo amines carboxamides ketones sulfonamides
ISSN号0947-6539
通讯作者石峰
中文摘要Complicated and expensive organic ligands are normally essential in fine chemical synthesis at preparative or industrial levels. The synthesis of fine chemicals by using heterogeneous catalyst systems without additive organic ligand is highly desirable but severely limited due to their poor generality and rigorous reaction conditions. Here, we show the results of carbon–nitrogen or carbon–carbonbond formation catalyzed by an Ag/Mo hybrid material with specific Ag6Mo10O33 crystal structure. 48 nitrogen-or oxygen-containing compounds, that is, amines, carboxamides, sulfonamides, and ketones, were successfully synthesized through a borrowing-hydrogen mechanism. Up to 99% isolated yields were obtained under relatively mild conditions without additive organic ligand. The catalytic process shows promise for the efficient and economic synthesis of amine, carboxamide, sulfonamide, and ketone derivatives because of the simplicity of the system and ease of operation.
学科主题物理化学
收录类别SCI
资助信息the “Hundred Talents Program” of the Chinese Academy of Sciences
语种英语
公开日期2012-12-04
源URL[http://210.77.64.217/handle/362003/2378]  
专题兰州化学物理研究所_绿色化学研究发展中心
通讯作者Shi F(石峰); Shi F(石峰)
推荐引用方式
GB/T 7714
Cui XJ,Shi F,Deng YQ,et al. Organic Ligand-Free Alkylation of Amines, Carboxamides, Sulfonamides,and Ketones by Using Alcohols Catalyzed by Heterogeneous Ag/Mo Oxides[J]. Chem. Eur. J.,2011,17:1021-1028.
APA 崔新江,石峰,邓友全,&石峰.(2011).Organic Ligand-Free Alkylation of Amines, Carboxamides, Sulfonamides,and Ketones by Using Alcohols Catalyzed by Heterogeneous Ag/Mo Oxides.Chem. Eur. J.,17,1021-1028.
MLA 崔新江,et al."Organic Ligand-Free Alkylation of Amines, Carboxamides, Sulfonamides,and Ketones by Using Alcohols Catalyzed by Heterogeneous Ag/Mo Oxides".Chem. Eur. J. 17(2011):1021-1028.

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来源:兰州化学物理研究所

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