A new noncentrosymmetric vanadoborate: synthesis, crystal structure and characterization of K2SrVB5O12
文献类型：期刊论文
| 作者 | Chen Songjie; Pan Shilie ; Zhao Wenwu; Yu Hongwei; Wu Hongping; Yang Zhihua; Yang Yun
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| 刊名 | Dalton Transactions
 |
| 出版日期 | 2012 |
| 卷号 | 41期号:30页码:9202-9208 |
| ISSN号 | 14779226 |
| 通讯作者 | Pan, SL |
| 中文摘要 | A new noncentrosymmetric vanadoborate compound, K2SrVB 5O12, is synthesized by the high temperature solution method. It crystallizes in the monoclinic space group P21 (no. 4) with lattice constants a = 6.618(3) A˚, b = 8.378(4) A˚, c = 9.974(5) A˚, β = 99.789(6)°, Z = 2. The structure consists of vanadoborate anionic layers with K+ and Sr2+ cations filling the void spaces via electrostatic interactions to form the three-dimensional network. The TG-DSC curves and the UV-Vis-NIR diffuse reflectance spectrum were measured. Band structures and density of states were calculated. The powder second harmonic generation (SHG) effect of K2SrVB5O12 is similar to that of KH2PO4 (KDP). |
| 学科主题 | Chemistry |
| 收录类别 | SCI |
| 公开日期 | 2012-11-29 |
| 源URL | [http://ir.xjipc.cas.cn/handle/365002/1372]  |
| 专题 | 新疆理化技术研究所_新疆维吾尔自治区电子信息材料与器件重点实验室 新疆理化技术研究所_材料物理与化学研究室 |
| 作者单位 | Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen Songjie,Pan Shilie,Zhao Wenwu,et al. A new noncentrosymmetric vanadoborate: synthesis, crystal structure and characterization of K2SrVB5O12[J]. Dalton Transactions,2012,41(30):9202-9208. |
| APA | Chen Songjie.,Pan Shilie.,Zhao Wenwu.,Yu Hongwei.,Wu Hongping.,...&Yang Yun.(2012).A new noncentrosymmetric vanadoborate: synthesis, crystal structure and characterization of K2SrVB5O12.Dalton Transactions,41(30),9202-9208. |
| MLA | Chen Songjie,et al."A new noncentrosymmetric vanadoborate: synthesis, crystal structure and characterization of K2SrVB5O12".Dalton Transactions 41.30(2012):9202-9208. |
入库方式： OAI收割
来源：新疆理化技术研究所
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