Synthesis, crystal structures and optical properties of two congruent-melting isotypic diphosphates: LiM3P2O7 (M = Na, K)
文献类型：期刊论文
| 作者 | Shi Yunjing; Wang Ying; Pan Shilie ; Yang Zhihua; Dong Xiaoyu; Wu Hongping; Zhang Min; Cao Jian; Zhou Zhongxiang
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| 刊名 | JOURNAL OF SOLID STATE CHEMISTRY
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| 出版日期 | 2012 |
| 卷号 | 197期号:1页码:128-133 |
| 关键词 | LiNa3P2O7 LiK3P2O7 Crystal structures X-ray diffraction Thermal analyses |
| ISSN号 | 224596 |
| 通讯作者 | Pan, SL |
| 中文摘要 | Two new isotypic diphosphates, LiNa3P2O7 (1) and LiK3P2O7 (2), have been synthesized by conventional solid-state reaction. The single-crystal X-ray structural analyses have shown that they crystallize in the orthorhombic space group C2221 (No. 20) with the unit cells: a=5.4966(2) A˚, b=9.1365(4) A˚, c=12.2764(5) A˚ for compound 1 and a=6.0373(14) A˚, b=9.339(2) A˚, c=13.292(3) A˚ for compound 2. The LiM3P2O7 (M=Na, K) consist of two-dimensional [LiP2O7]3- layers, which are composed by LiO4 tetrahedral and diphosphate groups, the Na or K atoms are filled in the interlayers and balance the charge. Second harmonic generation (SHG) on powder samples have been measured using Kurtz and Perry techniques. Thermal analyses, IR spectroscopy, UV-vis-NIR diffuse reflectance spectra, and band structure calculations are performed on the reported compounds. |
| 收录类别 | SCI |
| 资助信息 | National Natural Science Foundation of China U1129301, 51172277, 21101168, 11104344; Main Direction Program of Knowledge Innovation of Chinese Academy of Sciences KJCX2-EW-H03-03; One Hundred Talents Project Foundation Program of Chinese Academy of Sciences; Major Program of Xinjiang Uygur Autonomous Region of China during the 12th Five-Year Plan Period 201130111; High Technology Research and Development Program of Xinjiang Uygur Autonomous Region of China 201116143 |
| 公开日期 | 2012-11-29 |
| 源URL | [http://ir.xjipc.cas.cn/handle/365002/1376]  |
| 专题 | 新疆理化技术研究所_新疆维吾尔自治区电子信息材料与器件重点实验室 新疆理化技术研究所_材料物理与化学研究室 |
| 作者单位 | Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Univ, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shi Yunjing,Wang Ying,Pan Shilie,et al. Synthesis, crystal structures and optical properties of two congruent-melting isotypic diphosphates: LiM3P2O7 (M = Na, K)[J]. JOURNAL OF SOLID STATE CHEMISTRY,2012,197(1):128-133. |
| APA | Shi Yunjing.,Wang Ying.,Pan Shilie.,Yang Zhihua.,Dong Xiaoyu.,...&Zhou Zhongxiang.(2012).Synthesis, crystal structures and optical properties of two congruent-melting isotypic diphosphates: LiM3P2O7 (M = Na, K).JOURNAL OF SOLID STATE CHEMISTRY,197(1),128-133. |
| MLA | Shi Yunjing,et al."Synthesis, crystal structures and optical properties of two congruent-melting isotypic diphosphates: LiM3P2O7 (M = Na, K)".JOURNAL OF SOLID STATE CHEMISTRY 197.1(2012):128-133. |
入库方式： OAI收割
来源：新疆理化技术研究所
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