growth, structure and properties of the non-centrosymmetric hydrated borate can2b8o26h32
文献类型：期刊论文
| 作者 | Li Hongyi; Pan Shilie ; Wu Hongping; Yang Zhihua
|
| 刊名 | Materials Chemistry and Physics
 |
| 出版日期 | 2011 |
| 卷号 | 129期号:1-2页码:176-179 |
| 关键词 | Optical materials Crystal growth Powder diffraction Crystal structure |
| ISSN号 | 2540584 |
| 通讯作者 | Pan, SL |
| 英文摘要 | Nonlinear optical crystal of CaN2B8O 26H32 has been grown with sizes up to 9 × 8 × 5 mm3 by the solvent evaporation method. The structure was determined by single-crystal X-ray diffraction and further characterized by powder X-ray diffraction and IR spectrum analysis. CaN2B8O 26H32 crystallizes in the orthorhombic system, space group P212121, with unit-cell parameters a = 11.556(7) , b = 12.583(8) , c = 16.679(8) , Z = 4, V = 2425.2(2) 3, R1 = 0.0263, and wR2 = 0.0655. The structure is made up of CaO7 polyhedra, and [B4O5(OH) 4]2- polyborate anions, NH4+ cations, and H2O molecules. UV-vis-NIR diffuse reflectance spectrum is performed on the CaN2B8O26H32, which shows an absorption edge <190 nm in the UV region. Thermal properties were investigated by TG analyses. The powder second-harmonic generation intensity measured by the Kurtz-Perry method indicates that CaN 2B8O26H32 has about half times that of KH2PO4. |
| 学科主题 | Materials Science |
| 收录类别 | SCI |
| 公开日期 | 2012-11-29 |
| 源URL | [http://ir.xjipc.cas.cn/handle/365002/1422]  |
| 专题 | 新疆理化技术研究所_新疆维吾尔自治区电子信息材料与器件重点实验室 新疆理化技术研究所_材料物理与化学研究室 |
| 作者单位 | Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li Hongyi,Pan Shilie,Wu Hongping,et al. growth, structure and properties of the non-centrosymmetric hydrated borate can2b8o26h32[J]. Materials Chemistry and Physics,2011,129(1-2):176-179. |
| APA | Li Hongyi,Pan Shilie,Wu Hongping,&Yang Zhihua.(2011).growth, structure and properties of the non-centrosymmetric hydrated borate can2b8o26h32.Materials Chemistry and Physics,129(1-2),176-179. |
| MLA | Li Hongyi,et al."growth, structure and properties of the non-centrosymmetric hydrated borate can2b8o26h32".Materials Chemistry and Physics 129.1-2(2011):176-179. |
入库方式： OAI收割
来源：新疆理化技术研究所
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