Synthesis, crystal structure and optical properties of a novel sodium lead pentaborate, NaPbB5O9
文献类型：期刊论文
| 作者 | Zhang Min; Pan Shilie ; Han Jian; Zhou Zhongxiang
|
| 刊名 | Journal of Solid State Chemistry
 |
| 出版日期 | 2011 |
| 卷号 | 184期号:4页码:825-829 |
| 关键词 | NaPbB5O9 Borate Synthesis Crystal structure |
| ISSN号 | 224596 |
| 通讯作者 | Pan, SL |
| 英文摘要 | A novel sodium lead pentaborate, NaPbB5O9, has been successfully synthesized by standard solid-state reaction. The single-crystal X-ray structural analysis showed that NaPbB5O9 crystallizes in the monoclinic space group P21/c with a=6.5324(10) A˚, b=13.0234(2) A˚, c=8.5838(10) A˚, β=104.971(10)°, and Z=4. The crystal structure is composed of double ring [B5O 9]3- units, [PbO7] and [NaO7] polyhedra. [B5O9]3- groups connect with each other forming two-dimensional infinite ∞[B5O 9]3- layers, while [PbO7] and [NaO7] polyhedra are located between the layers. [PbO7] polyhedra linked together via corner-sharing O atom forming novel infinite ∞[PbO6] chains along the c axis. The thermal behavior, IR spectrum and the optical diffuse reflectance spectrum of NaPbB 5O9 were reported. |
| 学科主题 | Chemistry |
| 收录类别 | SCI |
| 公开日期 | 2012-11-29 |
| 源URL | [http://ir.xjipc.cas.cn/handle/365002/1433]  |
| 专题 | 新疆理化技术研究所_新疆维吾尔自治区电子信息材料与器件重点实验室 |
| 作者单位 | Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang Min,Pan Shilie,Han Jian,et al. Synthesis, crystal structure and optical properties of a novel sodium lead pentaborate, NaPbB5O9[J]. Journal of Solid State Chemistry,2011,184(4):825-829. |
| APA | Zhang Min,Pan Shilie,Han Jian,&Zhou Zhongxiang.(2011).Synthesis, crystal structure and optical properties of a novel sodium lead pentaborate, NaPbB5O9.Journal of Solid State Chemistry,184(4),825-829. |
| MLA | Zhang Min,et al."Synthesis, crystal structure and optical properties of a novel sodium lead pentaborate, NaPbB5O9".Journal of Solid State Chemistry 184.4(2011):825-829. |
入库方式： OAI收割
来源：新疆理化技术研究所
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