Synthesis, structure characterization and optical properties of a new tripotassium cadmium pentaborate, K3CdB5O10
文献类型：期刊论文
| 作者 | Yu Hongwei; Pan Shilie ; Wu Hongping; Han Jian; Dong Xiaoyu; Zhou Zhongxiang
|
| 刊名 | Journal of Solid State Chemistry
 |
| 出版日期 | 2011 |
| 卷号 | 184期号:7页码:1644-1648 |
| 关键词 | K3CdB5O10 Pentaborate Synthesis Crystal structure Optical property |
| ISSN号 | 224596 |
| 通讯作者 | Pan, SL |
| 中文摘要 | A new ternary borate oxide, K3CdB5O10, has been synthesized by solid-state reaction at 580 °C. The compound crystallizes in the monoclinic space group P21/n with a=7.6707 (7) A˚, b=19.1765 (17) A˚, c=7.8784 (6) A˚, β=115.6083 (49)°, and Z=4. The crystal structure consists of a two-dimensional infinite [CdB5O10] layer, which forms by connecting isolated double ring [B5O10] groups and CdO4 tetrahedra. K atoms filling in the interlayer and intralayer link the layers together and balance charge. The IR spectrum has been studied and confirmed the presence of both BO3 and BO4 groups, and the UVvis-IR diffuse reflectance spectrum exhibits a band gap of about 3.4 eV. The DSC analysis proves that K3CdB5O10 is a congruent melting compound. |
| 学科主题 | Chemistry |
| 收录类别 | SCI |
| 公开日期 | 2012-11-29 |
| 源URL | [http://ir.xjipc.cas.cn/handle/365002/1443]  |
| 专题 | 新疆理化技术研究所_新疆维吾尔自治区电子信息材料与器件重点实验室 |
| 作者单位 | Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yu Hongwei,Pan Shilie,Wu Hongping,et al. Synthesis, structure characterization and optical properties of a new tripotassium cadmium pentaborate, K3CdB5O10[J]. Journal of Solid State Chemistry,2011,184(7):1644-1648. |
| APA | Yu Hongwei,Pan Shilie,Wu Hongping,Han Jian,Dong Xiaoyu,&Zhou Zhongxiang.(2011).Synthesis, structure characterization and optical properties of a new tripotassium cadmium pentaborate, K3CdB5O10.Journal of Solid State Chemistry,184(7),1644-1648. |
| MLA | Yu Hongwei,et al."Synthesis, structure characterization and optical properties of a new tripotassium cadmium pentaborate, K3CdB5O10".Journal of Solid State Chemistry 184.7(2011):1644-1648. |
入库方式： OAI收割
来源：新疆理化技术研究所
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