Synthesis, crystal structure and optical properties of a new lead bismuth borate
文献类型：期刊论文
| 作者 | Zhao Wenwu; Pan Shilie ; Han Jian; Zhou Zhongxiang
|
| 刊名 | INORGANICA CHIMICA ACTA
 |
| 出版日期 | 2011 |
| 卷号 | 379期号:1页码:130-134 |
| 关键词 | PbBiBO(4) Powder synthesis Crystal structure UV-Vis-NIR Diffuse-Reflectance spectrum |
| ISSN号 | 0020-1693 |
| 通讯作者 | Pan, SL |
| 中文摘要 | A new phase of the compound PbBiBO(4) has been successfully synthesized via the standard solid-state reaction, and the crystal structure has been determined from X-ray monocrystal diffraction data. It crystallizes in orthorhombic space group Cmca (No. 64) with lattice constants a = 10.782(3) angstrom, b = 10.502(3) angstrom, c = 7.477(2) angstrom, Z = 8. The crystal structure is characterized by a three-dimensional structure consisting of BiO(6) octahedra, PbO(4) tetrahedra and BO(3) triangles. The BiO(6) octahedra compose the layers through the O(2) atoms and O(3) atoms along the 101 direction, which connects the BO(3) trigonal groups by sharing the O(3) and two O(1) atoms and links the PbO(4) tetrahedra through the O(2) atoms. The UV-Vis-NIR Diffuse-Reflectance spectrum shows that the ultraviolet cutoff edge for the PbBiBO(4) crystal is about 310 nm. Functional groups in the sample were identified by Infrared spectrum. |
| 学科主题 | Chemistry |
| 收录类别 | SCI |
| 资助信息 | National Natural Science Foundation of China 50802110, 21001114; Chinese Academy of Sciences; Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry 20091001; Natural Science Foundation of Xinjiang Uygur Autonomous Region of China 200821159, 2009211B33; Xinjiang Uygur Autonomous Region of China 200816120 |
| 公开日期 | 2012-11-29 |
| 源URL | [http://ir.xjipc.cas.cn/handle/365002/1650]  |
| 专题 | 新疆理化技术研究所_新疆维吾尔自治区电子信息材料与器件重点实验室 |
| 作者单位 | Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhao Wenwu,Pan Shilie,Han Jian,et al. Synthesis, crystal structure and optical properties of a new lead bismuth borate[J]. INORGANICA CHIMICA ACTA,2011,379(1):130-134. |
| APA | Zhao Wenwu,Pan Shilie,Han Jian,&Zhou Zhongxiang.(2011).Synthesis, crystal structure and optical properties of a new lead bismuth borate.INORGANICA CHIMICA ACTA,379(1),130-134. |
| MLA | Zhao Wenwu,et al."Synthesis, crystal structure and optical properties of a new lead bismuth borate".INORGANICA CHIMICA ACTA 379.1(2011):130-134. |
入库方式： OAI收割
来源：新疆理化技术研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。