Synthesis of High-Purity Methylal via Extractive Catalytic Distillation
文献类型：期刊论文
| 作者 | Liu, HZ (Liu, Hongzhong); Gao, HY (Gao, Hongyan); Ma, YB (Ma, Yubo); Gao, ZX (Gao, Zhixian); Eli, WMJ (Eli, Wumanjiang)[ |
| 刊名 | CHEMICAL ENGINEERING & TECHNOLOGY
 |
| 出版日期 | 2012 |
| 卷号 | 35期号:5页码:841-846 |
| 关键词 | Cation-exchange resin Extractive catalytic distillation Formalin Methanol Methylal |
| ISSN号 | 9307516 |
| 英文摘要 | An integrated continuous process, which combines catalytic distillation and extractive distillation in one column, is investigated for the synthesis of high-purity methylal from methanol and formalin in the presence of a cation-exchange resin catalyst. A feed with methanol:formaldehyde 2:1 molar ratio is chosen to evaluate the effects of operating parameters, such as extractant feeding position, ratio of extractant to feed, reflux ratio, and reboiler temperature, on the continuous synthesis of methylal. Under the optimum operating conditions and with water as extractant, the extractive catalytic distillation process operated continuously, producing a methylal purity of 98.7% (H2O: <1.30%) with 98.0% formaldehyde conversion. An integrated continuous process combining catalytic distillation and extractive distillation in one column is applied for high-purity methylal synthesis from methanol and formalin in the presence of a cation-exchange resin catalyst. Under optimum conditions, using water as extractant, the extractive catalytic distillation process provided a methylal purity of 98.7% with 98.0% formaldehyde conversion. © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |
| 学科主题 | Engineering |
| WOS记录号 | WOS:000303117700012 |
| 公开日期 | 2012-11-29 |
| 源URL | [http://ir.xjipc.cas.cn/handle/365002/1389]  |
| 专题 | 新疆理化技术研究所_新疆维吾尔自治区精细化工工程技术研究中心 |
| 作者单位 | Chinese Acad Sci, Shanxi Inst Coal Chem, Taiyuan 030001, Shanxi, Peoples R China;Yili Normal Univ, Yining, Peoples R China;Chinese Acad Sci, Grad Univ, Beijing, Peoples R China;Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Xinjiang, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, HZ ,Gao, HY ,Ma, YB ,et al. Synthesis of High-Purity Methylal via Extractive Catalytic Distillation[J]. CHEMICAL ENGINEERING & TECHNOLOGY,2012,35(5):841-846. |
| APA | Liu, HZ ,Gao, HY ,Ma, YB ,Gao, ZX ,&Eli, WMJ .(2012).Synthesis of High-Purity Methylal via Extractive Catalytic Distillation.CHEMICAL ENGINEERING & TECHNOLOGY,35(5),841-846. |
| MLA | Liu, HZ ,et al."Synthesis of High-Purity Methylal via Extractive Catalytic Distillation".CHEMICAL ENGINEERING & TECHNOLOGY 35.5(2012):841-846. |
入库方式： OAI收割
来源：新疆理化技术研究所
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