Dirhodium(II) Complexes of 2-(Sulfonylimino)pyrrolidine: Synthesis and Application in Catalytic Benzylic Oxidation
文献类型：期刊论文
| 作者 | Wusiman Abudureheman; Tusun Xiarepati; Lu Chong-Dao |
| 刊名 | EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
 |
| 出版日期 | 2012 |
| 期号 | 16页码:3088-3092 |
| 关键词 | Rhodium N ligands Bridging ligands Homogeneous catalysis Benzylic oxidation |
| ISSN号 | 1434-193X |
| 通讯作者 | Lu, CD |
| 英文摘要 | A new class of dirhodium(II) tetraamidinates derived from 2-(sulfonylimino)pyrrolidines has been prepared through ligand substitution by using dirhodium(II) acetate, in which (3,1) geometric isomers are formed predominantly. Among these complexes, (3,1)-Rh2(Msip)4, exhibits good catalytic performance in benzylic oxidation. In the presence of (3,1)-Rh2(Msip)4 a variety of benzylic derivatives, including strongly electron-deficient arylalkanes such as 1-ethyl-4-nitrobenzene, are readily oxidized in water by the inexpensive oxidant T-HYDRO (R) (70 wt.-% aqueous tert-butyl hydroperoxide). |
| 学科主题 | Chemistry |
| 收录类别 | SCI |
| WOS记录号 | WOS:000304083700007 |
| 公开日期 | 2012-11-29 |
| 源URL | [http://ir.xjipc.cas.cn/handle/365002/1626]  |
| 专题 | 新疆理化技术研究所_资源化学研究室 |
| 作者单位 | Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China;Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China; Xinjiang Normal Univ, Sch Chem & Chem Engn, Urumqi 830054, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wusiman Abudureheman,Tusun Xiarepati,Lu Chong-Dao. Dirhodium(II) Complexes of 2-(Sulfonylimino)pyrrolidine: Synthesis and Application in Catalytic Benzylic Oxidation[J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY,2012(16):3088-3092. |
| APA | Wusiman Abudureheman,Tusun Xiarepati,&Lu Chong-Dao.(2012).Dirhodium(II) Complexes of 2-(Sulfonylimino)pyrrolidine: Synthesis and Application in Catalytic Benzylic Oxidation.EUROPEAN JOURNAL OF ORGANIC CHEMISTRY(16),3088-3092. |
| MLA | Wusiman Abudureheman,et al."Dirhodium(II) Complexes of 2-(Sulfonylimino)pyrrolidine: Synthesis and Application in Catalytic Benzylic Oxidation".EUROPEAN JOURNAL OF ORGANIC CHEMISTRY .16(2012):3088-3092. |
入库方式： OAI收割
来源：新疆理化技术研究所
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