Highly Enantioselective Arylation of N-Tosylalkylaldimines Catalyzed by Rhodium-Diene Complexes
文献类型：期刊论文
| 作者 | Cui Z(崔哲) ; Yu HJ(于宏杰) ; Yang RF(杨瑞峰) ; Gao WY(高文运) ; Feng CG(冯陈国) ; Lin GQ(林国强) |
| 刊名 | J. Am. Chem. Soc.
 |
| 出版日期 | 2011 |
| 卷号 | 133期号:32页码:12394-12397 |
| ISSN号 | 0002-7863 |
| 其他题名 | Highly Enantioselective Arylation of N-Tosylalkylaldimines Catalyzed by Rhodium-Diene Complexes |
| 通讯作者 | 冯陈国 ; 林国强 |
| 英文摘要 | A highly enantioselective rhodium-catalyzed arylation of aliphatic N-tosylaldimines has been developed. The combination of chiral bicyclo[3.3.0]octadiene ligands, an active rhodium hydroxide complex, and neutral reaction conditions is the key to achieving high yield and enantioselectivity. The application of this method is demonstrated by the enantioselective synthesis of chiral 2-aryl pyrrolidines and piperidines in a one-pot procedure. Furthermore, excellent results are also obtained for the imine substrates with the more readily cleavable N-nosyl protecting group. |
| 学科主题 | 金属有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1021/ja2046217 |
| 语种 | 英语 |
| WOS记录号 | WOS:000294740000020 |
| 公开日期 | 2013-02-20 |
| 源URL | [http://202.127.28.38/handle/331003/16721]  |
| 专题 | 上海有机化学研究所_中科院天然产物有机化学重点实验室 |
| 推荐引用方式 GB/T 7714 | Cui Z,Yu HJ,Yang RF,et al. Highly Enantioselective Arylation of N-Tosylalkylaldimines Catalyzed by Rhodium-Diene Complexes[J]. J. Am. Chem. Soc.,2011,133(32):12394-12397. |
| APA | 崔哲,于宏杰,杨瑞峰,高文运,冯陈国,&林国强.(2011).Highly Enantioselective Arylation of N-Tosylalkylaldimines Catalyzed by Rhodium-Diene Complexes.J. Am. Chem. Soc.,133(32),12394-12397. |
| MLA | 崔哲,et al."Highly Enantioselective Arylation of N-Tosylalkylaldimines Catalyzed by Rhodium-Diene Complexes".J. Am. Chem. Soc. 133.32(2011):12394-12397. |
入库方式： OAI收割
来源：上海有机化学研究所
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