The reaction of organozinc reagents with triftuoroacylated phosphonates: Synthesis of trifluoromethytated alpha, beta-unsaturated esters with an active methylene moiety
文献类型：期刊论文
| 作者 | Shen YC(沈延昌) ; Ni JH(倪家宏) |
| 刊名 | Heteroatom Chem.
 |
| 出版日期 | 2004 |
| 卷号 | 15期号:4页码:289-292 |
| ISSN号 | 1042-7163 |
| 其他题名 | 有机锌化合物和三氟酰基膦酸的反应。合成具有活泼亚甲基的三氟甲基α,β－不饱和酸酯 |
| 通讯作者 | 沈延昌 |
| 英文摘要 | The consecutive reaction of phosphonates 1 with n-butyllithium, trifluoroacetic anhydride, and organozinc compounds gives trifluoromethylated alpha, beta-unsaturated esters with an active methylene moiety and predominant Z-selectivity in 54-78% (3 steps) yields. (C) 2004 Wiley Periodicals, Inc. |
| 学科主题 | 氟化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1002/hc.20018 |
| 语种 | 英语 |
| WOS记录号 | WOS:000221692900001 |
| 公开日期 | 2013-02-21 |
| 源URL | [http://202.127.28.38/handle/331003/17013]  |
| 专题 | 上海有机化学研究所_中科院有机氟化学重点实验室 |
| 推荐引用方式 GB/T 7714 | Shen YC,Ni JH. The reaction of organozinc reagents with triftuoroacylated phosphonates: Synthesis of trifluoromethytated alpha, beta-unsaturated esters with an active methylene moiety[J]. Heteroatom Chem.,2004,15(4):289-292. |
| APA | 沈延昌,&倪家宏.(2004).The reaction of organozinc reagents with triftuoroacylated phosphonates: Synthesis of trifluoromethytated alpha, beta-unsaturated esters with an active methylene moiety.Heteroatom Chem.,15(4),289-292. |
| MLA | 沈延昌,et al."The reaction of organozinc reagents with triftuoroacylated phosphonates: Synthesis of trifluoromethytated alpha, beta-unsaturated esters with an active methylene moiety".Heteroatom Chem. 15.4(2004):289-292. |
入库方式： OAI收割
来源：上海有机化学研究所
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