Stereospecific synthesis of trifluoromethylated vinyl sulfides
文献类型：期刊论文
| 作者 | Shen YC(沈延昌) ; Wang GP(王国平) |
| 刊名 | Synthesis
 |
| 出版日期 | 2005 |
| 期号 | 13页码:2183-2187 |
| ISSN号 | 0039-7881 |
| 其他题名 | 立体专一性地合成三氟甲基乙烯基硫化物 |
| 通讯作者 | 沈延昌 |
| 英文摘要 | The synthetic utility of fluorinated vinylstannanes has been explored. This methodology provides a convenient and simple synthesis of trifluoromethylated vinyl sulfides in 60-97% yields with the formation of the E-isomer exclusively. The reaction is stereospecific and of wide scope including various types of thiols (aryl, benzyl, alkyl thiols, and thiols with an ethoxycarbonyl moiety) used as substrates. A possible mechanism is proposed. |
| 学科主题 | 氟化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1055/s-2005-869998 |
| 语种 | 英语 |
| WOS记录号 | WOS:000231458200014 |
| 公开日期 | 2013-02-21 |
| 源URL | [http://202.127.28.38/handle/331003/17023]  |
| 专题 | 上海有机化学研究所_中科院有机氟化学重点实验室 |
| 推荐引用方式 GB/T 7714 | Shen YC,Wang GP. Stereospecific synthesis of trifluoromethylated vinyl sulfides[J]. Synthesis,2005(13):2183-2187. |
| APA | 沈延昌,&王国平.(2005).Stereospecific synthesis of trifluoromethylated vinyl sulfides.Synthesis(13),2183-2187. |
| MLA | 沈延昌,et al."Stereospecific synthesis of trifluoromethylated vinyl sulfides".Synthesis .13(2005):2183-2187. |
入库方式： OAI收割
来源：上海有机化学研究所
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