Preparation, properties and synthetic potentials of fluorous boronates
文献类型：期刊论文
| 作者 | Huang YG(黄焰根) ; Chen DJ(陈大军) ; Qing FL(卿凤翎) |
| 刊名 | Tetrahedron
 |
| 出版日期 | 2003 |
| 卷号 | 59期号:40页码:7879-7886 |
| ISSN号 | 0040-4020 |
| 其他题名 | 氟碳相硼酸酯的制备、性能及合成应用 |
| 通讯作者 | 卿凤翎 |
| 英文摘要 | A fluorous approach to the chemistry of boronic acids and its application in fluorous-phase techniques are described. Treatment of fluomus bromosilane 2 with allyl Grignard reagent followed by dihydroxylation provided fluorous diol 1. A series of boronic acids were attached to 1 by esterification. The formed fluorous boronates 4 were moisture sensitive and thus their synthetic potentials were limited. Thus a fluorous pinacol, 5, was designed and synthesized by treatment of fluorous bromosilane 2 with excess 2,3-dimethyl-2-butyenylmagnesium bromide 9 to afford fluorous tetramethyl ethene 8, and was dihydroxylated. Compound 5 was successfully used to prepare fluorous boronates in a one-pot process from organic bromides. We have demonstrated that olefin cross-metathesis can be caoied out in a fluorous version. It is noteworhy that all of the auorinated componnds reponed in this paper were purified by simple liquid extraction. |
| 学科主题 | 氟化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1016/j.tet.2003.08.034 |
| 语种 | 英语 |
| WOS记录号 | WOS:000185585800004 |
| 公开日期 | 2013-02-22 |
| 源URL | [http://202.127.28.38/handle/331003/17499]  |
| 专题 | 上海有机化学研究所_中科院有机氟化学重点实验室 |
| 推荐引用方式 GB/T 7714 | Huang YG,Chen DJ,Qing FL. Preparation, properties and synthetic potentials of fluorous boronates[J]. Tetrahedron,2003,59(40):7879-7886. |
| APA | 黄焰根,陈大军,&卿凤翎.(2003).Preparation, properties and synthetic potentials of fluorous boronates.Tetrahedron,59(40),7879-7886. |
| MLA | 黄焰根,et al."Preparation, properties and synthetic potentials of fluorous boronates".Tetrahedron 59.40(2003):7879-7886. |
入库方式： OAI收割
来源：上海有机化学研究所
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