Synthesis and utilization of trifluoromethylated amino alcohol ligands for the enantio selective Reformatsky reaction and addition of diethylzinc to N-(diphenylphosphinoyl)imine
文献类型：期刊论文
| 作者 | Xu XH(徐修华) ; Qiu XL(邱小龙) ; Qing FL(卿凤翎) |
| 刊名 | Tetrahedron
 |
| 出版日期 | 2008 |
| 卷号 | 64期号:30-31页码:7353-7361 |
| ISSN号 | 0040-4020 |
| 其他题名 | Synthesis and utilization of trifluoromethylated amino alcohol ligands for the enantio selective Reformatsky reaction and addition of diethylzinc to N-(diphenylphosphinoyl)imine |
| 通讯作者 | 卿凤翎 |
| 英文摘要 | A series of trifluoromethylated amino alcohol ligands, which had been designed and conveniently prepared, were successfully applied in the enantioselective Reformatsky reaction and addition of diethylzinc to N-(diphenylphosphinoyl)imine,respectively. The influence of the substituents on C-3 position and the amino moiety on the enantioselectivity has been carefully investigated. in the best cases, ligand lb exhibited good selectivity for the enantioseiective Reformatsky reaction in 86% ee and ligand 12d provided excellent enantioselectivity in the addition of cliethylzinc to N-(diphenylphospbinoyl)imine with 95% ee. (c) 2008 Elsevier Ltd. All rights reserved. |
| 学科主题 | 氟化学 ; 生命有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1016/j.tet.2008.05.043 |
| 语种 | 英语 |
| WOS记录号 | WOS:000257619700039 |
| 公开日期 | 2013-02-22 |
| 源URL | [http://202.127.28.38/handle/331003/17633]  |
| 专题 | 上海有机化学研究所_中科院有机氟化学重点实验室 |
| 推荐引用方式 GB/T 7714 | Xu XH,Qiu XL,Qing FL. Synthesis and utilization of trifluoromethylated amino alcohol ligands for the enantio selective Reformatsky reaction and addition of diethylzinc to N-(diphenylphosphinoyl)imine[J]. Tetrahedron,2008,64(30-31):7353-7361. |
| APA | 徐修华,邱小龙,&卿凤翎.(2008).Synthesis and utilization of trifluoromethylated amino alcohol ligands for the enantio selective Reformatsky reaction and addition of diethylzinc to N-(diphenylphosphinoyl)imine.Tetrahedron,64(30-31),7353-7361. |
| MLA | 徐修华,et al."Synthesis and utilization of trifluoromethylated amino alcohol ligands for the enantio selective Reformatsky reaction and addition of diethylzinc to N-(diphenylphosphinoyl)imine".Tetrahedron 64.30-31(2008):7353-7361. |
入库方式： OAI收割
来源：上海有机化学研究所
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