Hydrogen-bonded aryl amide macrocycles: Synthesis, single-crystal structures, and stacking interactions with fullerenes and coronene
文献类型:期刊论文
作者 | Zhu YY(朱元元) ; Li C(李闯) ; Li GY(李光玉) ; Jiang XK(蒋锡夔) ; Li ZT(黎占亭) |
刊名 | J. Org. Chem.
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出版日期 | 2008 |
卷号 | 73期号:5页码:1745-1751 |
ISSN号 | 0022-3263 |
其他题名 | 氢键介质的芳酰胺大环: 合成、晶体结构和与富勒烯的芳香作用 |
通讯作者 | 黎占亭 |
英文摘要 | [Graphics] Six hydrogen-bonded shape-persistent aryl amide macrocycles have been prepared by using one-step and (for some) step-by-step approaches. From the one-step reactions, 3 + 3, 2 + 2, or even 1 + 1 macrocycles were obtained in modest to good yields. The reaction selectivity was highly dependent on the structures of the precursors. The X-ray structural analysis of two methoxyl-bearing macrocycles revealed intramolecular hydrogen bonding and weak intermolecular stacking interaction; no column-styled stacking structures were observed. The H-1 (DOSY) NMR, UV-vis, and fluorescent experiments indicated that the new rigidified macrocycles complex fullerenes or coronene in chloroform through intermolecular,pi-stacking interaction. The association constants of the corresponding 1: 1 complexes have been determined if the stacking was able to cause important fluorescent quenching of the macrocycles or coronene. |
学科主题 | 物理有机化学 |
收录类别 | SCI |
原文出处 | http://dx.doi.org/10.1021/jo702046f |
语种 | 英语 |
WOS记录号 | WOS:000253595100009 |
公开日期 | 2013-01-16 |
源URL | [http://202.127.28.38/handle/331003/12718] ![]() |
专题 | 上海有机化学研究所_物理有机化学研究室 |
推荐引用方式 GB/T 7714 | Zhu YY,Li C,Li GY,et al. Hydrogen-bonded aryl amide macrocycles: Synthesis, single-crystal structures, and stacking interactions with fullerenes and coronene[J]. J. Org. Chem.,2008,73(5):1745-1751. |
APA | 朱元元,李闯,李光玉,蒋锡夔,&黎占亭.(2008).Hydrogen-bonded aryl amide macrocycles: Synthesis, single-crystal structures, and stacking interactions with fullerenes and coronene.J. Org. Chem.,73(5),1745-1751. |
MLA | 朱元元,et al."Hydrogen-bonded aryl amide macrocycles: Synthesis, single-crystal structures, and stacking interactions with fullerenes and coronene".J. Org. Chem. 73.5(2008):1745-1751. |
入库方式: OAI收割
来源:上海有机化学研究所
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