Self-Assembly of Vesicles from Amphiphilic Aromatic Amide-Based Oligomers
文献类型：期刊论文
| 作者 | Xu YX(徐云祥) ; Wang GT(王贵涛) ; Zhao X(赵新) ; Jiang XK(蒋锡夔) ; Li ZT(黎占亭) |
| 刊名 | Langmuir
 |
| 出版日期 | 2009 |
| 卷号 | 25期号:5页码:2684-2688 |
| ISSN号 | 0743-7463 |
| 其他题名 | 基于两亲性寡聚芳酰胺的囊泡自组装 |
| 通讯作者 | 赵新 ; 黎占亭 |
| 英文摘要 | A novel class of linear arylamide oligomers has been designed and synthesized from naphthalene-2,7-diamine and benzene-1,3,5-tricarboxylic acid segments. The molecules carry two (tert-butoxycarbonylamino) groups at the ends and one to three hydrophilic N,N-bis(2-(2-(2-methoxyethoxy)ethoxy)ethyl)amino groups at one side of the backbone. The oligomers self-assembled into vesicular structures in methanol as a result of ordered stacking of the oligomeric amide backbones, which were evidenced by SEM, AFM, TEM, and fluorescent micrography experiments. It was also found that the tert-butoxycarbonylamino groups at the ends played an important role in promoting the ordered stacking of the backbones. Structural factors that affected the self-assembly of the oligomers were investigated. A two-layer model that was supported by TEM has been proposed for the formation of the vesicular structures, which was driven by both the hydrogen bonding and aromatic stacking. |
| 学科主题 | 物理有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1021/la8034243 |
| 语种 | 英语 |
| WOS记录号 | WOS:000263770800025 |
| 公开日期 | 2013-01-16 |
| 源URL | [http://202.127.28.38/handle/331003/12742]  |
| 专题 | 上海有机化学研究所_物理有机化学研究室 |
| 推荐引用方式 GB/T 7714 | Xu YX,Wang GT,Zhao X,et al. Self-Assembly of Vesicles from Amphiphilic Aromatic Amide-Based Oligomers[J]. Langmuir,2009,25(5):2684-2688. |
| APA | 徐云祥,王贵涛,赵新,蒋锡夔,&黎占亭.(2009).Self-Assembly of Vesicles from Amphiphilic Aromatic Amide-Based Oligomers.Langmuir,25(5),2684-2688. |
| MLA | 徐云祥,et al."Self-Assembly of Vesicles from Amphiphilic Aromatic Amide-Based Oligomers".Langmuir 25.5(2009):2684-2688. |
入库方式： OAI收割
来源：上海有机化学研究所
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