Palladium-catalyzed asymmetric allylic substitutions by axially chiral P,S-, S,S-, and S,O-heterodonor ligands with a binaphthalene framework
文献类型：期刊论文
| 作者 | Shi M(施敏) ; Zhang W(张雯) |
| 刊名 | Tetrahedron-Asymmetry
 |
| 出版日期 | 2004 |
| 卷号 | 15期号:19页码:3161-3169 |
| 其他题名 | Palladium-Catalyzed Asymmetric Allylic Substitutions by Axially Chiral P,S-; S,S-; and S,O-Heterodonor Ligands with Binaphthalene Framework. |
| 通讯作者 | 施敏 |
| 英文摘要 | Axially chiral P,S-heterodonor ligand L1 is effective in the asymmetric allylic substitution of 1,3-diphenylpropenyl acetate with dimethyl malonate. its bidentate coordination pattern to a I'd metal center with both P and S atoms has been unambiguously established by X-ray diffraction and NMR spectroscopic analyses. Herein, we further disclose that axially chiral S,S-heterodonor ligands L2-L4 are also effective in the same reaction to give the allylic alkylation product in moderate to good ee. However, the corresponding S,O-heterodonor ligands are not as effective as the corresponding P,S- or S,S-heterodonor ligands in the same asymmetric reaction. (C) 2004 Elsevier Ltd. All rights reserved. |
| 学科主题 | 金属有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1016/j.tetasy.2004.08.008 |
| 语种 | 英语 |
| WOS记录号 | WOS:000224447500020 |
| 公开日期 | 2013-01-09 |
| 源URL | [http://202.127.28.38/handle/331003/9940]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Shi M,Zhang W. Palladium-catalyzed asymmetric allylic substitutions by axially chiral P,S-, S,S-, and S,O-heterodonor ligands with a binaphthalene framework[J]. Tetrahedron-Asymmetry,2004,15(19):3161-3169. |
| APA | Shi M,&Zhang W.(2004).Palladium-catalyzed asymmetric allylic substitutions by axially chiral P,S-, S,S-, and S,O-heterodonor ligands with a binaphthalene framework.Tetrahedron-Asymmetry,15(19),3161-3169. |
| MLA | Shi M,et al."Palladium-catalyzed asymmetric allylic substitutions by axially chiral P,S-, S,S-, and S,O-heterodonor ligands with a binaphthalene framework".Tetrahedron-Asymmetry 15.19(2004):3161-3169. |
入库方式： OAI收割
来源：上海有机化学研究所
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