Lithium Diisopropylamide-Mediated Carbolithiation Reactions of Vinylidenecyclopropanes and Further Transformations of the Adducts
文献类型：期刊论文
| 作者 | Lu JM(陆建梅) ; Shi M(施敏) |
| 刊名 | Chem.-Eur. J.
 |
| 出版日期 | 2009 |
| 卷号 | 15期号:24页码:6065-6073 |
| 其他题名 | LDA促进的亚乙烯基环丙烷碳锂化反应和产物的进一步转化 |
| 通讯作者 | 施敏 |
| 英文摘要 | Highly stereo- and regioselective carbolithiation reactions of vinylidenecyclopropanes 1 were realized by treatment with lithium diisopropylamide (LDA) in THF and by quenching with various electrophiles such as aryl or aliphatic aldehydes, ketones, enones or propargyl bromide. Transformation of these adducts such as vinylcyclopropenes and allenols was also performed in the presence of Lewis acid or Bronsted acid to provide the fused and conjugated aromatic products in good to high yields under mild conditions. |
| 学科主题 | 金属有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1002/chem.200900068 |
| 语种 | 英语 |
| WOS记录号 | WOS:000267278900025 |
| 公开日期 | 2013-01-09 |
| 源URL | [http://202.127.28.38/handle/331003/10278]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Lu JM,Shi M. Lithium Diisopropylamide-Mediated Carbolithiation Reactions of Vinylidenecyclopropanes and Further Transformations of the Adducts[J]. Chem.-Eur. J.,2009,15(24):6065-6073. |
| APA | Lu JM,&Shi M.(2009).Lithium Diisopropylamide-Mediated Carbolithiation Reactions of Vinylidenecyclopropanes and Further Transformations of the Adducts.Chem.-Eur. J.,15(24),6065-6073. |
| MLA | Lu JM,et al."Lithium Diisopropylamide-Mediated Carbolithiation Reactions of Vinylidenecyclopropanes and Further Transformations of the Adducts".Chem.-Eur. J. 15.24(2009):6065-6073. |
入库方式： OAI收割
来源：上海有机化学研究所
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