Ring-Opening Reaction of Methylenecyclopropanes Derived from Methylenecyclopropyl Aldehydes through Cope Rearrangement
文献类型：期刊论文
| 作者 | Tang XY(唐翔鹰) ; Wei Y(魏音) ; Shi M(施敏) |
| 刊名 | Eur. J. Org. Chem.
 |
| 出版日期 | 2010 |
| 期号 | 31页码:6038-6042 |
| 其他题名 | 从亚甲基环丙烷醛得到的亚甲基环丙烷的开环反应 |
| 通讯作者 | 魏音 ; 施敏 |
| 英文摘要 | Tandem Wittig reaction/Cope rearrangement of methylenecyclopropyl aldehydes 1 with cinnamyltriphenylphosphonium bromide afforded a convenient method for the synthesis of cyclopentene derivatives 2 in moderate yields in a one-pot manner. Dialkyl 2-[(2-methylenecyclopropyl)methylene]malonates 3 derived from methylenecyclopropyl aldehydes 1 could produce two kinds of cyclopentene derivatives, 4 and 5, in good total yields through a thermally induced Cope rearrangement upon heating at 100 degrees C. Plausible reaction mechanisms are discussed on the basis of previous reports and on control experiments. |
| 学科主题 | 金属有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1002/ejoc.201000880 |
| 语种 | 英语 |
| WOS记录号 | WOS:000284515800014 |
| 公开日期 | 2013-01-09 |
| 源URL | [http://202.127.28.38/handle/331003/10400]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Tang XY,Wei Y,Shi M. Ring-Opening Reaction of Methylenecyclopropanes Derived from Methylenecyclopropyl Aldehydes through Cope Rearrangement[J]. Eur. J. Org. Chem.,2010(31):6038-6042. |
| APA | Tang XY,Wei Y,&Shi M.(2010).Ring-Opening Reaction of Methylenecyclopropanes Derived from Methylenecyclopropyl Aldehydes through Cope Rearrangement.Eur. J. Org. Chem.(31),6038-6042. |
| MLA | Tang XY,et al."Ring-Opening Reaction of Methylenecyclopropanes Derived from Methylenecyclopropyl Aldehydes through Cope Rearrangement".Eur. J. Org. Chem. .31(2010):6038-6042. |
入库方式： OAI收割
来源：上海有机化学研究所
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