Chiral separation of 2,3-allenoic acid by capillary zone electrophoresis using cyclodextrin derivatives
文献类型：期刊论文
| 作者 | Xu X(许旭) ; Bao XL(鲍晓岭) ; Dong XW(董晓渭) ; Shi ZJ(施章杰) ; Yu ZQ(俞瞻前) ; Ma SM(麻生明) |
| 刊名 | Chirality
 |
| 出版日期 | 2003 |
| 卷号 | 15期号:2页码:201-205 |
| ISSN号 | 0899-0042 |
| 其他题名 | 毛细管电泳是用环糊精衍生物手性分离2，3－联烯酸 |
| 通讯作者 | 许旭 |
| 英文摘要 | In this paper, Five of six samples of 2,3-allenoic acid enantiomers were separated by capillary zone electrophoresis (CZE) using hydroxypropyl-β-cyclodextrin (HP-β-CD) and hydroxypropyl-γ-cyclodextrin (HP-γ-CD) as chiral selectors. Using HP-γ-CD for chiral separation, three of the six enantiomers were separated. Five experi-mental conditions including HP-β-CD concentration, pH, buffer concentration, tempera- ture, and running voltage were investigated for their influence on separation and migra- tion using enantiomers of 2-methyl-4-phenyl-2,3-butadienoic acid (A) and 2-(n-propyl)-4-phenyl-2,3-butadienoic acid (B) as samples. Good separation results were observed when [HP-β-CD] =3-12 mmol/L and pH = 7-9 for samples A and B. The temperature range of 15-25℃ can be selected for convenience. According to the chiral separation results, HP-β-CD and HP-γ-CD should be valuable selectors to separate 2,3-allenoic acids and HP-γ-CD was suggested to separate the 2,3-allenoic acid samples with a group at 4-position bulkier than phenyl. Chirality 15:201-205, 2003. |
| 学科主题 | 有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1002/chir.10172 |
| 语种 | 英语 |
| WOS记录号 | WOS:000180696800015 |
| 公开日期 | 2013-01-15 |
| 源URL | [http://202.127.28.38/handle/331003/11946]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Xu X,Bao XL,Dong XW,et al. Chiral separation of 2,3-allenoic acid by capillary zone electrophoresis using cyclodextrin derivatives[J]. Chirality,2003,15(2):201-205. |
| APA | 许旭,鲍晓岭,董晓渭,施章杰,俞瞻前,&麻生明.(2003).Chiral separation of 2,3-allenoic acid by capillary zone electrophoresis using cyclodextrin derivatives.Chirality,15(2),201-205. |
| MLA | 许旭,et al."Chiral separation of 2,3-allenoic acid by capillary zone electrophoresis using cyclodextrin derivatives".Chirality 15.2(2003):201-205. |
入库方式： OAI收割
来源：上海有机化学研究所
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