Pd(OAc)(2)-catalyzed cyclization of 2,3-allenoic acids in the presence of terminal alpha,beta-unsaturated alkynones: A one-pot highly stereoselective synthesis of 4-(3 '-Oxo-1 '(E)-alkenyl)-2(5H)-furanones
文献类型：期刊论文
| 作者 | Chen GF(陈国飞) ; Ceng R(曾荣) ; Gu ZH(顾振华) ; Fu CL(傅春玲) ; Ma SM(麻生明) |
| 刊名 | Org. Lett.
 |
| 出版日期 | 2008 |
| 卷号 | 10期号:19页码:4235-4238 |
| ISSN号 | 1523-7060 |
| 其他题名 | Pd(OAc)(2)-catalyzed cyclization of 2,3-allenoic acids in the presence of terminal alpha,beta-unsaturated alkynones: A one-pot highly stereoselective synthesis of 4-(3'-Oxo-1'(E)-alkenyl)-2(5H)-furanones |
| 通讯作者 | 麻生明 |
| 英文摘要 | The Pd(OAc)(2)-catalyzed cyclization reaction of 2,3-allenoic acids in the presence of terminal alpha,beta-unsaturated alkynones afforded an E/Z mixture of 4-(3'-oxo-1'-alkenyl)-2(5H)-furanones. A subsequent complete isomerization of the Z-isomer to E-isomer was observed in DMSO at 90 degrees C, which led to a highly stereoselective synthesis of 4-(3'-oxo-1'(E)-alkenyl)-2(5H)-furanones. A possible mechanism is proposed. |
| 学科主题 | 金属有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1021/6801610w |
| 语种 | 英语 |
| WOS记录号 | WOS:000259557700021 |
| 公开日期 | 2013-01-16 |
| 源URL | [http://202.127.28.38/handle/331003/12154]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Chen GF,Ceng R,Gu ZH,et al. Pd(OAc)(2)-catalyzed cyclization of 2,3-allenoic acids in the presence of terminal alpha,beta-unsaturated alkynones: A one-pot highly stereoselective synthesis of 4-(3 '-Oxo-1 '(E)-alkenyl)-2(5H)-furanones[J]. Org. Lett.,2008,10(19):4235-4238. |
| APA | 陈国飞,曾荣,顾振华,傅春玲,&麻生明.(2008).Pd(OAc)(2)-catalyzed cyclization of 2,3-allenoic acids in the presence of terminal alpha,beta-unsaturated alkynones: A one-pot highly stereoselective synthesis of 4-(3 '-Oxo-1 '(E)-alkenyl)-2(5H)-furanones.Org. Lett.,10(19),4235-4238. |
| MLA | 陈国飞,et al."Pd(OAc)(2)-catalyzed cyclization of 2,3-allenoic acids in the presence of terminal alpha,beta-unsaturated alkynones: A one-pot highly stereoselective synthesis of 4-(3 '-Oxo-1 '(E)-alkenyl)-2(5H)-furanones".Org. Lett. 10.19(2008):4235-4238. |
入库方式： OAI收割
来源：上海有机化学研究所
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