An efficient approach for monofluorination via highly regioselective fluorohydroxylation reaction of 3-aryl-1,2-allenes with selectfluor
文献类型:期刊论文
作者 | Zhou C(周超) ; Li J(李晶) ; Lv B(吕博) ; Fu CL(傅春玲) ; Ma SM(麻生明) |
刊名 | Org. Lett.
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出版日期 | 2008 |
卷号 | 10期号:4页码:581-583 |
ISSN号 | 1523-7060 |
其他题名 | An efficient approach for monofluorination via highly regioselective fluorohydroxylation reaction of 3-aryl-1,2-allenes with selectfluor |
通讯作者 | 傅春玲 ; 麻生明 |
英文摘要 | The internal C-C double bond in 3-aryl-1,2-allenes was highly regioselectively fluorohydroxylated to afford 2-fluoroalken-3-ols in 37-88% yields by using Selectfluor as the electrophilic reagent. The regioselectivity may be determined by the electronic effect, while the reactivity may be controlled by the stabilization effect of the aryl group in the allylic cationic intermediates. |
学科主题 | 有机化学 |
收录类别 | SCI |
原文出处 | http://dx.doi.org/10.1021/ol702863n |
语种 | 英语 |
WOS记录号 | WOS:000252989500015 |
公开日期 | 2013-01-16 |
源URL | [http://202.127.28.38/handle/331003/12176] ![]() |
专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
推荐引用方式 GB/T 7714 | Zhou C,Li J,Lv B,et al. An efficient approach for monofluorination via highly regioselective fluorohydroxylation reaction of 3-aryl-1,2-allenes with selectfluor[J]. Org. Lett.,2008,10(4):581-583. |
APA | 周超,李晶,吕博,傅春玲,&麻生明.(2008).An efficient approach for monofluorination via highly regioselective fluorohydroxylation reaction of 3-aryl-1,2-allenes with selectfluor.Org. Lett.,10(4),581-583. |
MLA | 周超,et al."An efficient approach for monofluorination via highly regioselective fluorohydroxylation reaction of 3-aryl-1,2-allenes with selectfluor".Org. Lett. 10.4(2008):581-583. |
入库方式: OAI收割
来源:上海有机化学研究所
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