中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Studies on highly regio- and stereoselective selenohydroxylation reaction of 1,2-allenyl phosphine oxides with PhSeCl

文献类型:期刊论文

作者He GK(何广科) ; Guo H(郭浩) ; Qian R(钱荣) ; Guo YL(郭寅龙) ; Fu CL(付春玲) ; Ma SM(麻生明)
刊名Tetrahedron
出版日期2009
卷号65期号:25页码:4877-4889
ISSN号0040-4020
其他题名1,2-联烯磷氧化物和PhSeCl的高区域和立体选择性硒羟基化反应研究
通讯作者麻生明
英文摘要The selenohydroxylation of readily available 1,2-allenyl phosphine oxides with PhSeCl in MeCN/H2O afforded 3-hydroxy-2-phenylselanyl-1(E)-alkenyl diphenyl phosphine oxides in good yields with very high regio- and stereoselectivities including the high efficiency of the axial chirality transfer. The E-stereoselectivity is believed to be determined by the neighboring group participation effect of the diphenyl phosphine oxide functionality. (C) 2009 Elsevier Ltd. All rights reserved.
学科主题金属有机化学
收录类别SCI
原文出处http://dx.doi.org/10.1016/j.tet.2009.04.023
语种英语
WOS记录号WOS:000267009400015
公开日期2013-01-16
源URL[http://202.127.28.38/handle/331003/12196]  
专题上海有机化学研究所_金属有机化学国家重点实验室
推荐引用方式
GB/T 7714
He GK,Guo H,Qian R,et al. Studies on highly regio- and stereoselective selenohydroxylation reaction of 1,2-allenyl phosphine oxides with PhSeCl[J]. Tetrahedron,2009,65(25):4877-4889.
APA 何广科,郭浩,钱荣,郭寅龙,付春玲,&麻生明.(2009).Studies on highly regio- and stereoselective selenohydroxylation reaction of 1,2-allenyl phosphine oxides with PhSeCl.Tetrahedron,65(25),4877-4889.
MLA 何广科,et al."Studies on highly regio- and stereoselective selenohydroxylation reaction of 1,2-allenyl phosphine oxides with PhSeCl".Tetrahedron 65.25(2009):4877-4889.

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来源:上海有机化学研究所

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