An Efficient Synthesis of Terminal Allenes from Terminal 1-Alkynes
文献类型：期刊论文
| 作者 | Kuang JQ(况锦强) ; Ma SM(麻生明) |
| 刊名 | J. Org. Chem.
 |
| 出版日期 | 2009 |
| 卷号 | 74期号:4页码:1763-1765 |
| ISSN号 | 0022-3263 |
| 其他题名 | 一种有效从端炔合成端联烯的方法 |
| 通讯作者 | 麻生明 |
| 英文摘要 | We have developed a modified method for the synthesis of terminal allenes from terminal 1-alkyne: The reaction of 1-alkynes with 1.8 equiv of Cy2NH and 2.5 equiv of paraformaldehyde mediated by CuI (0.5 equiv) in refluxing dioxane may produce terminal allenes in much higher yields than the previously reported protocol and many functional groups such as mesylate, hydroxyl group, ether, amide, etc. may be tolerated. |
| 学科主题 | 有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1021/jo802391x |
| 语种 | 英语 |
| WOS记录号 | WOS:000263316600048 |
| 公开日期 | 2013-01-16 |
| 源URL | [http://202.127.28.38/handle/331003/12202]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Kuang JQ,Ma SM. An Efficient Synthesis of Terminal Allenes from Terminal 1-Alkynes[J]. J. Org. Chem.,2009,74(4):1763-1765. |
| APA | 况锦强,&麻生明.(2009).An Efficient Synthesis of Terminal Allenes from Terminal 1-Alkynes.J. Org. Chem.,74(4),1763-1765. |
| MLA | 况锦强,et al."An Efficient Synthesis of Terminal Allenes from Terminal 1-Alkynes".J. Org. Chem. 74.4(2009):1763-1765. |
入库方式： OAI收割
来源：上海有机化学研究所
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