One-Pot Synthesis of 1,3-Disubstituted Allenes from 1-Alkynes, Aldehydes, and Morpholine
文献类型：期刊论文
| 作者 | Kuang JQ(况锦强) ; Ma SM(麻生明) |
| 刊名 | J. Am. Chem. Soc.
 |
| 出版日期 | 2010 |
| 卷号 | 132期号:6页码:1786-1787 |
| ISSN号 | 0002-7863 |
| 其他题名 | 由1-烷基炔,醛和吗啉出发合成1,3-二取代联烯的一步法策略 |
| 通讯作者 | 麻生明 |
| 英文摘要 | ZnI2 has been identified as the catalyst for the one-step synthesis of allenes from terminal alkynes and aldehydes with morpholine as the base ill toluene. The reaction is believed to proceed via the intermediacy of propargylic amines. which was converted to allenes by a sequential hydride transfer and beta-elimination process. The reaction is applicable for both aromatic and aliphatic aldehydes. Functionalities such as halide, hydroxyl, or amine may be tolerated. |
| 学科主题 | 有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1021/ja910503k |
| 语种 | 英语 |
| WOS记录号 | WOS:000275085000027 |
| 公开日期 | 2013-01-16 |
| 源URL | [http://202.127.28.38/handle/331003/12218]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Kuang JQ,Ma SM. One-Pot Synthesis of 1,3-Disubstituted Allenes from 1-Alkynes, Aldehydes, and Morpholine[J]. J. Am. Chem. Soc.,2010,132(6):1786-1787. |
| APA | 况锦强,&麻生明.(2010).One-Pot Synthesis of 1,3-Disubstituted Allenes from 1-Alkynes, Aldehydes, and Morpholine.J. Am. Chem. Soc.,132(6),1786-1787. |
| MLA | 况锦强,et al."One-Pot Synthesis of 1,3-Disubstituted Allenes from 1-Alkynes, Aldehydes, and Morpholine".J. Am. Chem. Soc. 132.6(2010):1786-1787. |
入库方式： OAI收割
来源：上海有机化学研究所
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