Carbon-Carbon Double-Bond Isomerization and Diels-Alder Reaction of Dimethyl 5-Methylene-4-isopropylidene-2-cycloheptene-1,1-dicarboxylate with Dienophiles
文献类型：期刊论文
| 作者 | Lu P(陆平) ; Kuang JQ(况锦强) ; Ma SM(麻生明) |
| 刊名 | Synlett
 |
| 出版日期 | 2010 |
| 期号 | 2页码:227-230 |
| ISSN号 | 0936-5214 |
| 其他题名 | 在5-亚甲基-4-异丁烯基-2-环庚烯-1,1-二甲酯与亲双烯体作用时发生的碳碳双键异构化及Diels-Alder反应 |
| 通讯作者 | 麻生明 |
| 英文摘要 | Tricyclic compounds were obtained as a single diastereomer via carbon-carbon double-bond isomerization-Diels-Alder reaction of dimethyl 5-methylene-4-isopropylidene-2-cycloheptene-1,1-dicarboxylate with dienophiles under the catalysis of [RhCl(cod)(2)](2)/dppe/AgOTf. Further experiments provided the proof of isomerization of carbon-carbon double bond. Meanwhile a sequential double Diels-Alder reaction took place without carbon carbon double-bond isomerization when 4-phenyl-4H-1,2,4-triazole-3,5-dione used as a dienophile. |
| 学科主题 | 有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1055/s-0029-1218574 |
| 语种 | 英语 |
| WOS记录号 | WOS:000274334900011 |
| 公开日期 | 2013-01-16 |
| 源URL | [http://202.127.28.38/handle/331003/12220]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Lu P,Kuang JQ,Ma SM. Carbon-Carbon Double-Bond Isomerization and Diels-Alder Reaction of Dimethyl 5-Methylene-4-isopropylidene-2-cycloheptene-1,1-dicarboxylate with Dienophiles[J]. Synlett,2010(2):227-230. |
| APA | 陆平,况锦强,&麻生明.(2010).Carbon-Carbon Double-Bond Isomerization and Diels-Alder Reaction of Dimethyl 5-Methylene-4-isopropylidene-2-cycloheptene-1,1-dicarboxylate with Dienophiles.Synlett(2),227-230. |
| MLA | 陆平,et al."Carbon-Carbon Double-Bond Isomerization and Diels-Alder Reaction of Dimethyl 5-Methylene-4-isopropylidene-2-cycloheptene-1,1-dicarboxylate with Dienophiles".Synlett .2(2010):227-230. |
入库方式： OAI收割
来源：上海有机化学研究所
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