Stereoselective synthesis and structural characterization of rac-planar chiral bis(2-methoxyethylindenyl)lanthanum and yttrium tetrahydroborates
文献类型：期刊论文
| 作者 | Qian ZT(钱长涛) ; Zou G(邹刚) ; Nie WL(聂万丽) ; Sun J(孙杰) ; Dmitri A. ; Lemenovskii ; Maxim V. Borzov |
| 刊名 | Polyhedron
 |
| 出版日期 | 2000 |
| 卷号 | 19期号:16-17页码:1955-1959 |
| ISSN号 | 0277-5387 |
| 其他题名 | 平面手性双(2-甲氧乙基茚)镧氢化物外消旋体的立体选择性合成和结构测定 |
| 通讯作者 | 钱长涛 |
| 英文摘要 | Racemic planar chiral metallocenes bis(2-methoxyethylindenyl) yttrium and lanthanum tetrahydroborates (MeOCH^2CH^2C^9H^6)^2Lnμ2-H)nBH^4-n (Lu = Y, n = 2(1); Ln = La, n = 3, (2)) have been stereoselectively isolated in high yield by reaction of the corresponding lanthanoeene chlorides with sodium borohydride in THF at room temperature. The two complexes have been fully characterized by elemental analyses, MS. ~1H NMR and IR spectra. The tetrahydroborate ion has been identified as slipped bidentate (μ^2-H)^2BH^2 and tridentate (μ^2H)^3BH ligands in I and 2, respectively. 2000 Elsevier Science Ltd. All rights reserved. |
| 学科主题 | 金属有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1016/S0277-5387(00)00479-4 |
| 语种 | 英语 |
| WOS记录号 | WOS:000089771100010 |
| 公开日期 | 2013-01-22 |
| 源URL | [http://202.127.28.38/handle/331003/15211]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Qian ZT,Zou G,Nie WL,et al. Stereoselective synthesis and structural characterization of rac-planar chiral bis(2-methoxyethylindenyl)lanthanum and yttrium tetrahydroborates[J]. Polyhedron,2000,19(16-17):1955-1959. |
| APA | 钱长涛.,邹刚.,聂万丽.,孙杰.,Dmitri A..,...&Maxim V. Borzov.(2000).Stereoselective synthesis and structural characterization of rac-planar chiral bis(2-methoxyethylindenyl)lanthanum and yttrium tetrahydroborates.Polyhedron,19(16-17),1955-1959. |
| MLA | 钱长涛,et al."Stereoselective synthesis and structural characterization of rac-planar chiral bis(2-methoxyethylindenyl)lanthanum and yttrium tetrahydroborates".Polyhedron 19.16-17(2000):1955-1959. |
入库方式： OAI收割
来源：上海有机化学研究所
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