Bis-(2-diphenylphosphinoethyl)cyclopentadienylchlorolutetium: synthesis and dynamic behavior in solution
文献类型：期刊论文
| 作者 | D. M. Roitershtein ; D. P. Krutko ; E. N. Veksler ; D. A. Lemenovskii ; Nie WL(聂万丽) ; Qian ZT(钱长涛) |
| 刊名 | Russ. Chem. Bull.
 |
| 出版日期 | 2001 |
| 卷号 | 50期号:7页码:1295-1298 |
| ISSN号 | 1066-5285 |
| 其他题名 | 双(2-二苯膦乙基〕环戊二烯基氯化镥的合成及溶液动力学性质 |
| 通讯作者 | D. P. Krutko |
| 英文摘要 | The new biscyclopentadienyl lutetium complex (η~5η~1-C^5H^4CH^2CH^2PPh^2)^2LuCl was synthesized by the reaction of LuCl^3(THG)^3 with lithium (2-diphenylphosphinoethyl)cyclopentadienide. Its behavior in solution was investigated by dynamic NMR spectroscopy. It was shown that the coordination of both phosphino groups to the lutetium center is retained over the whole temperature range studied. The barrier to pseudo-rotation for the trigonal bipyramid, which governs the intramolecular dynamics of this complex, was determined. |
| 学科主题 | 金属有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1023/A:1014031512361 |
| 语种 | 英语 |
| WOS记录号 | WOS:000173332000032 |
| 公开日期 | 2013-01-22 |
| 源URL | [http://202.127.28.38/handle/331003/15235]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | D. M. Roitershtein,D. P. Krutko,E. N. Veksler,et al. Bis-(2-diphenylphosphinoethyl)cyclopentadienylchlorolutetium: synthesis and dynamic behavior in solution[J]. Russ. Chem. Bull.,2001,50(7):1295-1298. |
| APA | D. M. Roitershtein,D. P. Krutko,E. N. Veksler,D. A. Lemenovskii,聂万丽,&钱长涛.(2001).Bis-(2-diphenylphosphinoethyl)cyclopentadienylchlorolutetium: synthesis and dynamic behavior in solution.Russ. Chem. Bull.,50(7),1295-1298. |
| MLA | D. M. Roitershtein,et al."Bis-(2-diphenylphosphinoethyl)cyclopentadienylchlorolutetium: synthesis and dynamic behavior in solution".Russ. Chem. Bull. 50.7(2001):1295-1298. |
入库方式： OAI收割
来源：上海有机化学研究所
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