Polymeric chain structures of substituted (Dimethylfluorenylsilyl)cyclopentadienyl lithium and sodium compounds
文献类型:期刊论文
作者 | Nie WL(聂万丽) ; Qian ZT(钱长涛) ; Chen YF(陈耀峰) ; Sun J(孙杰) |
刊名 | Organometallics
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出版日期 | 2001 |
卷号 | 20期号:26页码:5780-5783 |
ISSN号 | 0276-7333 |
其他题名 | 具有聚合链结构的二甲基异基硅基取代环戊二烯锂和钠化合物 |
通讯作者 | 钱长涛 |
英文摘要 | Summary: reaction of the dimethylsily-bridged flourene cyclopentadiene ligand with 1 equiv of n-butylithium or sodium hydride smoothly afforded the corresponding monoalkali=metal salts [(FluMe^2Si)Cp]M.(THF)^n(Cp=C^5H^4Flu=C^13H^9)(M=Li(1),n=0; M=Na(2), n=1).Complexes 1 and 2 were characterized by single crystal X-ray structural analyses. These revealed that both of then have similar linear polymeric structural aggregate types in the solid state. In complexes 1 and 2, the fluorenyldimethylsily groups attached to the cyclopentadienyl rings are arranged in gaps and oriented on the same side of the multideck chain. |
学科主题 | 金属有机化学 |
收录类别 | SCI |
原文出处 | http://dx.doi.org/10.1021/om0104823 |
语种 | 英语 |
WOS记录号 | WOS:000172939800048 |
公开日期 | 2013-01-22 |
源URL | [http://202.127.28.38/handle/331003/15237] ![]() |
专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
推荐引用方式 GB/T 7714 | Nie WL,Qian ZT,Chen YF,et al. Polymeric chain structures of substituted (Dimethylfluorenylsilyl)cyclopentadienyl lithium and sodium compounds[J]. Organometallics,2001,20(26):5780-5783. |
APA | 聂万丽,钱长涛,陈耀峰,&孙杰.(2001).Polymeric chain structures of substituted (Dimethylfluorenylsilyl)cyclopentadienyl lithium and sodium compounds.Organometallics,20(26),5780-5783. |
MLA | 聂万丽,et al."Polymeric chain structures of substituted (Dimethylfluorenylsilyl)cyclopentadienyl lithium and sodium compounds".Organometallics 20.26(2001):5780-5783. |
入库方式: OAI收割
来源:上海有机化学研究所
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