中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Polymeric chain structures of substituted (Dimethylfluorenylsilyl)cyclopentadienyl lithium and sodium compounds

文献类型:期刊论文

作者Nie WL(聂万丽) ; Qian ZT(钱长涛) ; Chen YF(陈耀峰) ; Sun J(孙杰)
刊名Organometallics
出版日期2001
卷号20期号:26页码:5780-5783
ISSN号0276-7333
其他题名具有聚合链结构的二甲基异基硅基取代环戊二烯锂和钠化合物
通讯作者钱长涛
英文摘要Summary: reaction of the dimethylsily-bridged flourene cyclopentadiene ligand with 1 equiv of n-butylithium or sodium hydride smoothly afforded the corresponding monoalkali=metal salts [(FluMe^2Si)Cp]M.(THF)^n(Cp=C^5H^4Flu=C^13H^9)(M=Li(1),n=0; M=Na(2), n=1).Complexes 1 and 2 were characterized by single crystal X-ray structural analyses. These revealed that both of then have similar linear polymeric structural aggregate types in the solid state. In complexes 1 and 2, the fluorenyldimethylsily groups attached to the cyclopentadienyl rings are arranged in gaps and oriented on the same side of the multideck chain.
学科主题金属有机化学
收录类别SCI
原文出处http://dx.doi.org/10.1021/om0104823
语种英语
WOS记录号WOS:000172939800048
公开日期2013-01-22
源URL[http://202.127.28.38/handle/331003/15237]  
专题上海有机化学研究所_金属有机化学国家重点实验室
推荐引用方式
GB/T 7714
Nie WL,Qian ZT,Chen YF,et al. Polymeric chain structures of substituted (Dimethylfluorenylsilyl)cyclopentadienyl lithium and sodium compounds[J]. Organometallics,2001,20(26):5780-5783.
APA 聂万丽,钱长涛,陈耀峰,&孙杰.(2001).Polymeric chain structures of substituted (Dimethylfluorenylsilyl)cyclopentadienyl lithium and sodium compounds.Organometallics,20(26),5780-5783.
MLA 聂万丽,et al."Polymeric chain structures of substituted (Dimethylfluorenylsilyl)cyclopentadienyl lithium and sodium compounds".Organometallics 20.26(2001):5780-5783.

入库方式: OAI收割

来源:上海有机化学研究所

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