Iron porphyrin-catalyzed olefination of ketenes with diazoacetate for the enantioselective synthesis of allenes
文献类型:期刊论文
作者 | Li CY(李传莹) ; Wang XB(王小兵) ; Sun XL(孙秀丽) ; Tang Y(唐勇) ; Zheng JC(郑君成) ; Xu ZH(徐政虎) ; Zhou YG(周永贵) ; Dai LX(戴立信) |
刊名 | J. Am. Chem. Soc.
![]() |
出版日期 | 2007 |
卷号 | 129期号:6页码:1494-1495 |
ISSN号 | 0002-7863 |
其他题名 | Iron porphyrin-catalyzed olefination of ketenes with diazoacetate for the enantioselective synthesis of allenes |
通讯作者 | 唐勇 ; 周永贵 |
英文摘要 | In the presence of Ph3P and catalytic Fe(TCP) Cl, ketenes could react with EDA to give allenes in high yields under neutral conditions for the first time. By employing chiral phosphine instead of PPh3, allenes could be synthesized with high enantioselectivity (93-98% ee) in good yields. |
学科主题 | 金属有机化学 |
收录类别 | SCI |
原文出处 | http://dx.doi.org/10.1021/ja068642v |
语种 | 英语 |
WOS记录号 | WOS:000244000700011 |
公开日期 | 2013-02-19 |
源URL | [http://202.127.28.38/handle/331003/15959] ![]() |
专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
推荐引用方式 GB/T 7714 | Li CY,Wang XB,Sun XL,et al. Iron porphyrin-catalyzed olefination of ketenes with diazoacetate for the enantioselective synthesis of allenes[J]. J. Am. Chem. Soc.,2007,129(6):1494-1495. |
APA | 李传莹.,王小兵.,孙秀丽.,唐勇.,郑君成.,...&戴立信.(2007).Iron porphyrin-catalyzed olefination of ketenes with diazoacetate for the enantioselective synthesis of allenes.J. Am. Chem. Soc.,129(6),1494-1495. |
MLA | 李传莹,et al."Iron porphyrin-catalyzed olefination of ketenes with diazoacetate for the enantioselective synthesis of allenes".J. Am. Chem. Soc. 129.6(2007):1494-1495. |
入库方式: OAI收割
来源:上海有机化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。