An Efficient Diphosphine/Hybrid-Amine Combination for Ruthenium(II)-Catalyzed Asymmetric Hydrogenation of Aryl Ketones
文献类型：期刊论文
| 作者 | Li YH(李跃辉) ; ZHOU YOUGUI ; Shi QX(石奇勋) ; Ding KL(丁奎岭) ; NOYORI RYOJI ; SANDOVAL CHRISTIAN A |
| 刊名 | Adv. Synth. Catal.
 |
| 出版日期 | 2011 |
| 卷号 | 353期号:2-3页码:495-500 |
| ISSN号 | 1615-4150 |
| 其他题名 | An Efficient Diphosphine/Hybrid-Amine Combination for Ruthenium(II)-Catalyzed Asymmetric Hydrogenation of Aryl Ketones |
| 通讯作者 | SANDOVAL CHRISTIAN A |
| 英文摘要 | Readily available and modular hybrid amine/benzimidazole-based 1H-benzimidazole-2-methanamine (BIMA) ligands in combination with 2,3-O-isopropylidene-2,3-dihydroxy-1,4-bis(diphenylphosphino) butane (DIOP) afford efficient catalytic systems for the ruthenium(II)-catalyzed asymmetric hydrogenation (AH) of a number of aryl ketones. The AH proceeds smoothly with substrate-to-catalyst (S/C) molar ratios of up to 100,000 (TOF of 6500 h(-1), 8 atm) giving chiral alcohols in up to 99% ee. |
| 学科主题 | 金属有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1002/adsc.201000577 |
| 语种 | 英语 |
| WOS记录号 | WOS:000287669600036 |
| 公开日期 | 2013-02-22 |
| 源URL | [http://202.127.28.38/handle/331003/17887]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Li YH,ZHOU YOUGUI,Shi QX,et al. An Efficient Diphosphine/Hybrid-Amine Combination for Ruthenium(II)-Catalyzed Asymmetric Hydrogenation of Aryl Ketones[J]. Adv. Synth. Catal.,2011,353(2-3):495-500. |
| APA | 李跃辉,ZHOU YOUGUI,石奇勋,丁奎岭,NOYORI RYOJI,&SANDOVAL CHRISTIAN A.(2011).An Efficient Diphosphine/Hybrid-Amine Combination for Ruthenium(II)-Catalyzed Asymmetric Hydrogenation of Aryl Ketones.Adv. Synth. Catal.,353(2-3),495-500. |
| MLA | 李跃辉,et al."An Efficient Diphosphine/Hybrid-Amine Combination for Ruthenium(II)-Catalyzed Asymmetric Hydrogenation of Aryl Ketones".Adv. Synth. Catal. 353.2-3(2011):495-500. |
入库方式： OAI收割
来源：上海有机化学研究所
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