中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Study of the corrosion mechanism of the in situ grown Mg-Al-CO32- hydrotalcite film on AZ31 alloy

文献类型:期刊论文

作者J. Chen ; Y. W. Song ; D. Y. Shan ; E. H. Han
刊名Corrosion Science
出版日期2012
卷号65页码:268-277
关键词Magnesium EIS XPS XRD Passive films layered double hydroxides conversion film magnesium alloy anion-exchange mg alloy carbonic-acid resistance ion crystallization immobilization
ISSN号0010-938X
中文摘要The corrosion mechanism of Mg-Al-CO32- hydrotalcite film is discussed based on its corrosion behavior and the anion-exchange or adsorption effect of Cl-. The results demonstrate that the film is very compact and acts as a barrier against Cl- attack in the early stage. Then the surface of the film is dissolved gradually due to its instability in aqueous solutions. Only after eliminating CO32-, Cl- can insert into the hydrotalcite interlayer to balance charges. Cl- cannot substitute CO32- just in NaCl solution, but can adsorb on active spots of the film to accelerate the decomposition. (C) 2012 Elsevier Ltd. All rights reserved.
原文出处://WOS:000311192800031
公开日期2013-02-05
源URL[http://ir.imr.ac.cn/handle/321006/59903]  
专题金属研究所_中国科学院金属研究所
推荐引用方式
GB/T 7714
J. Chen,Y. W. Song,D. Y. Shan,et al. Study of the corrosion mechanism of the in situ grown Mg-Al-CO32- hydrotalcite film on AZ31 alloy[J]. Corrosion Science,2012,65:268-277.
APA J. Chen,Y. W. Song,D. Y. Shan,&E. H. Han.(2012).Study of the corrosion mechanism of the in situ grown Mg-Al-CO32- hydrotalcite film on AZ31 alloy.Corrosion Science,65,268-277.
MLA J. Chen,et al."Study of the corrosion mechanism of the in situ grown Mg-Al-CO32- hydrotalcite film on AZ31 alloy".Corrosion Science 65(2012):268-277.

入库方式: OAI收割

来源:金属研究所

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