Study of the corrosion mechanism of the in situ grown Mg-Al-CO32- hydrotalcite film on AZ31 alloy
文献类型:期刊论文
作者 | J. Chen ; Y. W. Song ; D. Y. Shan ; E. H. Han |
刊名 | Corrosion Science
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出版日期 | 2012 |
卷号 | 65页码:268-277 |
关键词 | Magnesium EIS XPS XRD Passive films layered double hydroxides conversion film magnesium alloy anion-exchange mg alloy carbonic-acid resistance ion crystallization immobilization |
ISSN号 | 0010-938X |
中文摘要 | The corrosion mechanism of Mg-Al-CO32- hydrotalcite film is discussed based on its corrosion behavior and the anion-exchange or adsorption effect of Cl-. The results demonstrate that the film is very compact and acts as a barrier against Cl- attack in the early stage. Then the surface of the film is dissolved gradually due to its instability in aqueous solutions. Only after eliminating CO32-, Cl- can insert into the hydrotalcite interlayer to balance charges. Cl- cannot substitute CO32- just in NaCl solution, but can adsorb on active spots of the film to accelerate the decomposition. (C) 2012 Elsevier Ltd. All rights reserved. |
原文出处 | |
公开日期 | 2013-02-05 |
源URL | [http://ir.imr.ac.cn/handle/321006/59903] ![]() |
专题 | 金属研究所_中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | J. Chen,Y. W. Song,D. Y. Shan,et al. Study of the corrosion mechanism of the in situ grown Mg-Al-CO32- hydrotalcite film on AZ31 alloy[J]. Corrosion Science,2012,65:268-277. |
APA | J. Chen,Y. W. Song,D. Y. Shan,&E. H. Han.(2012).Study of the corrosion mechanism of the in situ grown Mg-Al-CO32- hydrotalcite film on AZ31 alloy.Corrosion Science,65,268-277. |
MLA | J. Chen,et al."Study of the corrosion mechanism of the in situ grown Mg-Al-CO32- hydrotalcite film on AZ31 alloy".Corrosion Science 65(2012):268-277. |
入库方式: OAI收割
来源:金属研究所
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