The influence of Zr substitution for Nb on the corrosion behaviors of the Ni-Nb-Zr bulk metallic glasses
文献类型:期刊论文
作者 | D. K. Li ; Z. W. Zhu ; H. F. Zhang ; A. M. Wang ; Z. Q. Hu |
刊名 | Science China-Physics Mechanics & Astronomy
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出版日期 | 2012 |
卷号 | 55期号:12页码:2362-2366 |
关键词 | bulk metallic glasses corrosion resistance X-ray photoelectron spectroscopy forming ability mechanical-properties thermal-stability high-strength alloys resistance ti elements system al |
ISSN号 | 1674-7348 |
中文摘要 | The influence of Zr content on corrosion behaviors of the Ni61.5Nb38.5-x Zr (x) (x=1, 3, 5, 7, 9 at.%) bulk metallic glasses (BMGs) in 1 M HCl aqueous solution was investigated by potentiodynamic polarization measurements and X-ray photo-electron spectroscopy (XPS). It was found that these BMG alloys possess superior corrosion resistance, that is, with large passive region of about 1.5 V and low passive current density (as low as 0.05 Am-2 for Ni61.5Nb31.5Zr7). XPS analysis indicates that the high corrosion resistance is attributed to the formation of Nb- and Zr-enriched surface films formed in the aggressive acid solution. The Zr substitution for Nb effectively reduces the Ni content, particularly the metallic state Ni content in the surface films, which depresses the electrical conduction of the surface films and reduces the passive current density, thus leading to the enhancement of the corrosion resistance of these Ni-Nb-Zr BMGs. These alloys may potentially be useful for engineering applications. |
原文出处 | |
公开日期 | 2013-02-05 |
源URL | [http://ir.imr.ac.cn/handle/321006/60051] ![]() |
专题 | 金属研究所_中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | D. K. Li,Z. W. Zhu,H. F. Zhang,et al. The influence of Zr substitution for Nb on the corrosion behaviors of the Ni-Nb-Zr bulk metallic glasses[J]. Science China-Physics Mechanics & Astronomy,2012,55(12):2362-2366. |
APA | D. K. Li,Z. W. Zhu,H. F. Zhang,A. M. Wang,&Z. Q. Hu.(2012).The influence of Zr substitution for Nb on the corrosion behaviors of the Ni-Nb-Zr bulk metallic glasses.Science China-Physics Mechanics & Astronomy,55(12),2362-2366. |
MLA | D. K. Li,et al."The influence of Zr substitution for Nb on the corrosion behaviors of the Ni-Nb-Zr bulk metallic glasses".Science China-Physics Mechanics & Astronomy 55.12(2012):2362-2366. |
入库方式: OAI收割
来源:金属研究所
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