Preparation of highly-ordered mesoporous carbons by organic-organic self-assembly using the reverse amphiphilic triblock copolymer PPO-PEO-PPO with a long hydrophilic chain
文献类型：期刊论文
| 作者 | P. Li ; Y. Song ; Q. Y. Lin ; J. L. Shi ; L. Liu ; L. L. He ; H. Q. Ye ; Q. G. Guo |
| 刊名 | Microporous and Mesoporous Materials
 |
| 出版日期 | 2012 |
| 卷号 | 159页码:81-86 |
| 关键词 | Mesostructure Reverse block copolymer Carbon methanol fuel-cell nanoporous carbon molecular-sieves phenolic resin template transformation performance fabrication frameworks storage |
| ISSN号 | 1387-1811 |
| 中文摘要 | A family of highly ordered mesoporous carbons (OMCs) were prepared by the organic-organic self-assembly of a reverse amphiphilic triblock copolymer with a soluble in ethanol, low-molecular-molar phenolic resin. The self-assembly was induced by evaporation. Small angle X-ray scattering, transmission electron microscopy and nitrogen adsorption/desorption isotherms evaluated by the Brunauer-Emmett-Teller method have been used to characterize the OMCs. Phase transitions from a lamellar (L infinity) one dimensional pore system with pore size centered at 6.3 nm to a hexagonal (p6mm) two dimensional pore system with tunable pore size from 3.5-3.9 nm, to a cubic (Fc (3) over bar -m) three dimensional cagelike pore system with a tri-modal pore structure and finally to another disordered cubic mesoporous carbons, are observed by finely tuning the molar ratios of the phenol/formaldehyde/NaOH/template. All the OMCs had high surface area and a uniform pore size. The results show that by increasing the hydrophilicity of the system by changing the molar ratios of reactants, the mesophase can be tailored conveniently. Furthermore, these transitions help us understand the mechanism of the formation of mesophase to produce different OMCs. (C) 2012 Elsevier Inc. All rights reserved. |
| 原文出处 | |
| 公开日期 | 2013-02-05 |
| 源URL | [http://ir.imr.ac.cn/handle/321006/60062]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | P. Li,Y. Song,Q. Y. Lin,et al. Preparation of highly-ordered mesoporous carbons by organic-organic self-assembly using the reverse amphiphilic triblock copolymer PPO-PEO-PPO with a long hydrophilic chain[J]. Microporous and Mesoporous Materials,2012,159:81-86. |
| APA | P. Li.,Y. Song.,Q. Y. Lin.,J. L. Shi.,L. Liu.,...&Q. G. Guo.(2012).Preparation of highly-ordered mesoporous carbons by organic-organic self-assembly using the reverse amphiphilic triblock copolymer PPO-PEO-PPO with a long hydrophilic chain.Microporous and Mesoporous Materials,159,81-86. |
| MLA | P. Li,et al."Preparation of highly-ordered mesoporous carbons by organic-organic self-assembly using the reverse amphiphilic triblock copolymer PPO-PEO-PPO with a long hydrophilic chain".Microporous and Mesoporous Materials 159(2012):81-86. |
入库方式： OAI收割
来源：金属研究所
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