The oxidation of soot particulate in the presence of NO2
文献类型：期刊论文
| 作者 | J. O. Muller ; B. Frank ; R. E. Jentoft ; R. Schlogl ; D. S. Su |
| 刊名 | Catalysis Today
 |
| 出版日期 | 2012 |
| 卷号 | 191期号:1页码:106-111 |
| 关键词 | Carbon Microstructure Surface functionalization Thermogravimetry Kinetics Combustion diesel-engine soot carbon nanotubes low-emission model soot combustion particles kinetics microstructure oxygen black |
| ISSN号 | 0920-5861 |
| 中文摘要 | The microstructure of soot-like carbons is correlated with their reactivity toward combustion. The focus of this study is on Euro IV heavy duty diesel engine soot. Additionally, two soot samples providing lower and larger particle sizes as their most striking property are taken as references. The effect of NO2 addition to the O-2-containing gas feed is investigated. It is found that NO2 accelerates the oxidation of soot in the low-temperature region (250-400 degrees C) due to an increased surface functionalization with oxygen groups and a subsequent decomposition thereof. Accordingly, initially highly functionalized soot is less susceptible to this effect. The apparent activation energy of combustion is remarkably lowered in the presence of NO2. It is found that the total reactivity correlates with microstructural features such as surface functionalization, size and curvature of basic structural units, stack height, and particle diameter. (c) 2012 Elsevier B.V. All rights reserved. |
| 原文出处 | |
| 公开日期 | 2013-02-05 |
| 源URL | [http://ir.imr.ac.cn/handle/321006/60165]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | J. O. Muller,B. Frank,R. E. Jentoft,et al. The oxidation of soot particulate in the presence of NO2[J]. Catalysis Today,2012,191(1):106-111. |
| APA | J. O. Muller,B. Frank,R. E. Jentoft,R. Schlogl,&D. S. Su.(2012).The oxidation of soot particulate in the presence of NO2.Catalysis Today,191(1),106-111. |
| MLA | J. O. Muller,et al."The oxidation of soot particulate in the presence of NO2".Catalysis Today 191.1(2012):106-111. |
入库方式： OAI收割
来源：金属研究所
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