Dual-heteroatom-modified ordered mesoporous carbon: Hydrothermal functionalization, structure, and its electrochemical performance
文献类型：期刊论文
| 作者 | X. C. Zhao ; Q. Zhang ; B. S. Zhang ; C. M. Chen ; A. Q. Wang ; T. Zhang ; D. S. Su |
| 刊名 | Journal of Materials Chemistry
 |
| 出版日期 | 2012 |
| 卷号 | 22期号:11页码:4963-4969 |
| 关键词 | oxidative dehydrogenation activated carbons oxygen reduction electron-spectroscopy sensitivity factors nitrogen-content porous carbon supercapacitors nanotubes boron |
| ISSN号 | 0959-9428 |
| 中文摘要 | The diverse applications of ordered mesoporous carbons (OMCs) are not only bonded to their superior structural properties, but also to their chemical properties. The termination of graphene sheets in OMCs provides abundant sites for heteroatom decoration to mediate their chemical properties. In this contribution, boron and phosphorus were co-incorporated into OMCs via a facile aqueous self-assembly taking advantage of a hydrothermal doping strategy. The as-obtained B/P-modified OMCs process a large surface area of ca. 600 m(2) g(-1), and a uniform pore size of ca. 6.3 nm, as well as long range ordering. By varying the hydrothermal synthesis temperature, the concentration of B and P introduced can be controlled from 0.8 to 1.6 wt% and from 2.3 to 3.6 wt%, respectively. The interaction of heteroatom B and P was enhanced when the hydrothermal temperature is above 100 degrees C. The heteroatom-containing groups were firmly embedded and homogeneously distributed on the carbon frameworks. When the B/P co-modified OMCs were applied as electrodes in supercapacitors, they presented promising performance compared with B- or/and P-modified OMC obtained without hydrothermal treatment. |
| 原文出处 | |
| 公开日期 | 2013-02-05 |
| 源URL | [http://ir.imr.ac.cn/handle/321006/60486]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | X. C. Zhao,Q. Zhang,B. S. Zhang,et al. Dual-heteroatom-modified ordered mesoporous carbon: Hydrothermal functionalization, structure, and its electrochemical performance[J]. Journal of Materials Chemistry,2012,22(11):4963-4969. |
| APA | X. C. Zhao.,Q. Zhang.,B. S. Zhang.,C. M. Chen.,A. Q. Wang.,...&D. S. Su.(2012).Dual-heteroatom-modified ordered mesoporous carbon: Hydrothermal functionalization, structure, and its electrochemical performance.Journal of Materials Chemistry,22(11),4963-4969. |
| MLA | X. C. Zhao,et al."Dual-heteroatom-modified ordered mesoporous carbon: Hydrothermal functionalization, structure, and its electrochemical performance".Journal of Materials Chemistry 22.11(2012):4963-4969. |
入库方式： OAI收割
来源：金属研究所
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