Monte Carlo Simulation of the Radius of Gyration of Hyperbranched Polymers Formed in Self-condensing Vinyl Polymerization System in the Presence of Core Initiators with Unequal Reactivity
文献类型：期刊论文
| 作者 | Y. Zheng ; H. J. Wang |
| 刊名 | Chemical Journal of Chinese Universities-Chinese
 |
| 出版日期 | 2012 |
| 卷号 | 33期号:1页码:144-148 |
| 关键词 | Self-condensing vinyl polymerization Unequal reactivity Radius of gyration Monte Carlo simulation molecular-weight distribution multifunctional initiator rate constants kinetic-model parameters monomers |
| ISSN号 | 0251-0790 |
| 中文摘要 | The second radius of gyration of hyperbranched polymers formed in self-condensing vinyl polymerization system in the presence of core initiators was studied by the method of Monte Carlo simulation, in which the unequal reactivity was taken into account. As a result, the roles of the reactivity differences in two types of active groups, the molar ratio and functionality of core initiators were mainly discussed, and it was found that these factors could give rise to a significant influence on the radius of gyration of hyperbranched polymers with and without a core initiator. This provides some useful clues for regulating the dimension of the hyperbranched polymers in the relevant experiments. |
| 原文出处 | |
| 公开日期 | 2013-02-05 |
| 源URL | [http://ir.imr.ac.cn/handle/321006/60513]  |
| 专题 | 金属研究所_中国科学院金属研究所 |
| 推荐引用方式 GB/T 7714 | Y. Zheng,H. J. Wang. Monte Carlo Simulation of the Radius of Gyration of Hyperbranched Polymers Formed in Self-condensing Vinyl Polymerization System in the Presence of Core Initiators with Unequal Reactivity[J]. Chemical Journal of Chinese Universities-Chinese,2012,33(1):144-148. |
| APA | Y. Zheng,&H. J. Wang.(2012).Monte Carlo Simulation of the Radius of Gyration of Hyperbranched Polymers Formed in Self-condensing Vinyl Polymerization System in the Presence of Core Initiators with Unequal Reactivity.Chemical Journal of Chinese Universities-Chinese,33(1),144-148. |
| MLA | Y. Zheng,et al."Monte Carlo Simulation of the Radius of Gyration of Hyperbranched Polymers Formed in Self-condensing Vinyl Polymerization System in the Presence of Core Initiators with Unequal Reactivity".Chemical Journal of Chinese Universities-Chinese 33.1(2012):144-148. |
入库方式： OAI收割
来源：金属研究所
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