Aza-Morita-Baylis-Hillman reactions of N-(benzylidene)polyfluoroanilines with methyl acrylate and acrylonitrile
文献类型：期刊论文
| 作者 | Liu XY(刘心源) ; Chai Z(柴卓) ; Zhao G(赵刚) ; Zhu SZ(朱仕正) |
| 刊名 | J. Fluor. Chem.
 |
| 出版日期 | 2005 |
| 卷号 | 126期号:8页码:1215-1221 |
| ISSN号 | 0022-1139 |
| 其他题名 | 羧酸高效促进醛的烯丙基化反应 |
| 通讯作者 | 赵刚 ; 朱仕正 |
| 英文摘要 | Aza-Morita-Baylis-Hiliman reactions of N-(benzylidene)polyfluoroanilines 1 with methyl acrylate or acrylonitrile were studied. It was found that Lewis base, solvent and reaction temperature can significantly affect the reaction. Using 3-hydroxyquinuclidine (3-HQD) as a Lewis base in the reactions of 1 with methyl acrylate in DMF, the normal aza-Morita-Baylis-Hillman adducts 3 were formed in moderate to excellent yields. For the reactions of I with acrylonitrile, 1,4-diazabicyclo[2.2.2] octane (DABCO) is the best Lewis base giving the corresponding aza-Morita-Baylis-Hillman adducts 4 as the sole product in good to moderate yield. However, upon treatment of I with acrolein 2c, the Corresponding reaction did not occur even in the presence of a variety of catalysts. (c) 2005 Elsevier B.V. All rights reserved. |
| 学科主题 | 有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1016/j.jfluchem.2005.05.010 |
| 语种 | 英语 |
| WOS记录号 | WOS:000231275300013 |
| 公开日期 | 2013-02-26 |
| 源URL | [http://202.127.28.38/handle/331003/20679]  |
| 专题 | 上海有机化学研究所_中科院天然产物有机化学重点实验室 |
| 推荐引用方式 GB/T 7714 | Liu XY,Chai Z,Zhao G,et al. Aza-Morita-Baylis-Hillman reactions of N-(benzylidene)polyfluoroanilines with methyl acrylate and acrylonitrile[J]. J. Fluor. Chem.,2005,126(8):1215-1221. |
| APA | 刘心源,柴卓,赵刚,&朱仕正.(2005).Aza-Morita-Baylis-Hillman reactions of N-(benzylidene)polyfluoroanilines with methyl acrylate and acrylonitrile.J. Fluor. Chem.,126(8),1215-1221. |
| MLA | 刘心源,et al."Aza-Morita-Baylis-Hillman reactions of N-(benzylidene)polyfluoroanilines with methyl acrylate and acrylonitrile".J. Fluor. Chem. 126.8(2005):1215-1221. |
入库方式： OAI收割
来源：上海有机化学研究所
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