Organocatalyzed Friedel–Craft-type reaction of 2-naphthol with b,c-unsaturated a-keto ester to form novel optically active naphthopyran derivatives
文献类型:期刊论文
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作者 | Wang XS(王晓生) ; Zheng CW(郑昌武) ; Zhao SL(赵胜利) ; Chai Z(柴卓) ; Zhao G(赵刚) ; Yang GS(杨高升) |
刊名 | Tetrahedron-Asymmetry
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出版日期 | 2008-01-01 |
卷号 | 19期号:23页码:2699-2704 |
ISSN号 | 0957-4166 |
其他题名 | 有机催化付-克反应合成手性萘并吡喃 |
通讯作者 | 赵刚 ; 杨高升 |
中文摘要 | A novel bifunctional thiourea–tertiary-amine-catalyzed enantioselective Friedel–Craft-type addition reaction of 2-naphthol with b,c-unsaturated a-keto ester was developed. Subsequent dehydration of the reaction adducts with a catalytic amount of concentrated H2SO4 in a one-pot fashion readily afforded a series of new optically active naphthopyran derivatives with moderate to good yields (up to 91%) and enantioselectivities (up to 90%). |
学科主题 | 天然产物有机化学 |
收录类别 | SCI |
原文出处 | http://dx.doi.org/10.1016/j.tetasy.2008.11.025 |
语种 | 英语 |
公开日期 | 2013-02-26 |
源URL | [http://ir.sioc.ac.cn/handle/331003/20775] ![]() |
专题 | 上海有机化学研究所_中科院天然产物有机化学重点实验室 |
推荐引用方式 GB/T 7714 | Wang XS,Zheng CW,Zhao SL,et al. Organocatalyzed Friedel–Craft-type reaction of 2-naphthol with b,c-unsaturated a-keto ester to form novel optically active naphthopyran derivatives, 有机催化付-克反应合成手性萘并吡喃[J]. Tetrahedron-Asymmetry,2008,19(23):2699-2704. |
APA | 王晓生,郑昌武,赵胜利,柴卓,赵刚,&杨高升.(2008).Organocatalyzed Friedel–Craft-type reaction of 2-naphthol with b,c-unsaturated a-keto ester to form novel optically active naphthopyran derivatives.Tetrahedron-Asymmetry,19(23),2699-2704. |
MLA | 王晓生,et al."Organocatalyzed Friedel–Craft-type reaction of 2-naphthol with b,c-unsaturated a-keto ester to form novel optically active naphthopyran derivatives".Tetrahedron-Asymmetry 19.23(2008):2699-2704. |
入库方式: OAI收割
来源:上海有机化学研究所
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