Studies of gas-phase fragmentation reactions of [Pd(PPh3)(2)(OCOR)](+) by electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry
文献类型：期刊论文
| 作者 | Qian R(钱荣) ; Guo H(郭浩) ; Liao YX(廖远熹) ; Wang HY(王昊阳) ; Zhang X(张祥) ; Guo YL(郭寅龙) |
| 刊名 | Rapid Commun. Mass Spectrom.
 |
| 出版日期 | 2006 |
| 卷号 | 20期号:4页码:589-594 |
| ISSN号 | 0951-4198 |
| 其他题名 | 用电喷雾离子化傅立叶质谱研究 [Pd(PPh3)2(OCOR)]I气相离子反应 |
| 通讯作者 | 郭寅龙 |
| 英文摘要 | Gas-phase fragmentation reactions of [Pd(PPh3)(2)(OCOR)](+) (R = H, CH3, CD3, C2H5, n-C3H7, n-C6H13 and C6H5) were studied by electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI-FTICRMS). In sustained off-resonance irradiation collision-activated dissociation (SORI-CAD) experiments, the complexes all dissociated to yield the same product ion at m/z 629.1. We propose that the fragmentation pathway occurs through the elimination of RCOOH and a palladium(IV) hydride intermediate. Semi-empirical (PM3) calculations shed light on the mechanism for the fragmentation reactions of these compounds. The results of deuterium-labeling experiments indicate that the protons of RCOOH lost from [Pd(PPh3)2(OCR)](+) originate from the phenyl in the triphenylphosphine ligand. [Pd(PPh3)(2)(OCOH)](+) undergoes two competitive pathways in SORICAD experiments, one of which is similar to that of [Pd(PPh3)(2)(OCOR)](+) (R = CH3, CD3, C2H5, n-C3H7, n-C6H13 and C6H5), and the other involves decarboxylation. The present study demonstrates that MS could play an important role in studying the gas-phase chemistry of palladium hydrides. Copyright (c) 2006 John Wiley & Sons, Ltd. |
| 学科主题 | 分析化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1002/rcm.2348 |
| 语种 | 英语 |
| WOS记录号 | WOS:000235485800010 |
| 公开日期 | 2013-02-25 |
| 源URL | [http://202.127.28.38/handle/331003/19926]  |
| 专题 | 上海有机化学研究所_分析化学研究室 |
| 推荐引用方式 GB/T 7714 | Qian R,Guo H,Liao YX,et al. Studies of gas-phase fragmentation reactions of [Pd(PPh3)(2)(OCOR)](+) by electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry[J]. Rapid Commun. Mass Spectrom.,2006,20(4):589-594. |
| APA | 钱荣,郭浩,廖远熹,王昊阳,张祥,&郭寅龙.(2006).Studies of gas-phase fragmentation reactions of [Pd(PPh3)(2)(OCOR)](+) by electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry.Rapid Commun. Mass Spectrom.,20(4),589-594. |
| MLA | 钱荣,et al."Studies of gas-phase fragmentation reactions of [Pd(PPh3)(2)(OCOR)](+) by electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry".Rapid Commun. Mass Spectrom. 20.4(2006):589-594. |
入库方式： OAI收割
来源：上海有机化学研究所
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