Mechanistic Insights into the Palladium(II)-catalyzed Intramolecular Cyclization of o-Alkynylphenylphosphonamide and N-(o-Alkynylphenyl)acetamide by Electrospray Ionization Mass Spectrometry
文献类型：期刊论文
| 作者 | Zhou J(周静) ; Tang W(唐伟) ; Guo YL(郭寅龙) ; Ding YX(丁贻祥) |
| 刊名 | Chin. J. Chem.
 |
| 出版日期 | 2009 |
| 卷号 | 27期号:9页码:1733-1740 |
| ISSN号 | 1001-604X |
| 其他题名 | 电喷雾质谱法研究钯催化的o-Alkynylphenylphosphonamide与 N-(o-Alkynylphenyl)acetamide 分子内环化反应机理 |
| 通讯作者 | 郭寅龙 ; 丁贻祥 |
| 英文摘要 | The intramolecular cyclization of o-alkynylphenylphosphonamide and N-(o-alkynylphenyl)acetamide was monitored by electrospray ionization mass spectrometry (ESI-MS) and its tandem version (ESI-MS/MS). The proposed intermediates were successfully intercepted and characterized. In addition, the intermediates composed of the substrate coordinated to the palladium(II) center in the reaction of o-alkynylphenylphosphonamide were unexpected before, and this interesting phenomenon of the substrate coordination seems associated with the unique structure of substrates. |
| 学科主题 | 有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1002/cjoc.200990292 |
| 语种 | 英语 |
| WOS记录号 | WOS:000270211000017 |
| 公开日期 | 2013-02-25 |
| 源URL | [http://202.127.28.38/handle/331003/19978]  |
| 专题 | 上海有机化学研究所_分析化学研究室 |
| 推荐引用方式 GB/T 7714 | Zhou J,Tang W,Guo YL,et al. Mechanistic Insights into the Palladium(II)-catalyzed Intramolecular Cyclization of o-Alkynylphenylphosphonamide and N-(o-Alkynylphenyl)acetamide by Electrospray Ionization Mass Spectrometry[J]. Chin. J. Chem.,2009,27(9):1733-1740. |
| APA | 周静,唐伟,郭寅龙,&丁贻祥.(2009).Mechanistic Insights into the Palladium(II)-catalyzed Intramolecular Cyclization of o-Alkynylphenylphosphonamide and N-(o-Alkynylphenyl)acetamide by Electrospray Ionization Mass Spectrometry.Chin. J. Chem.,27(9),1733-1740. |
| MLA | 周静,et al."Mechanistic Insights into the Palladium(II)-catalyzed Intramolecular Cyclization of o-Alkynylphenylphosphonamide and N-(o-Alkynylphenyl)acetamide by Electrospray Ionization Mass Spectrometry".Chin. J. Chem. 27.9(2009):1733-1740. |
入库方式： OAI收割
来源：上海有机化学研究所
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