Electrophilic aromatic substitution and single-electron transfer (SET) by the phenylium ion in the gas phase: characterization of a long-lived SET intermediate
文献类型：期刊论文
| 作者 | Yao SJ(姚胜军) ; Zhang X(张祥) ; Zhou J(周静) ; Qian R(钱荣) ; Xu Z(许哲) ; Fang F(方芳) ; Wei YL(魏远隆) ; Wang CH(王翠红) ; Yuan S(袁帅) ; Guo YL(郭寅龙) |
| 刊名 | J. Mass Spectrom.
 |
| 出版日期 | 2009 |
| 卷号 | 44期号:1页码:32-39 |
| ISSN号 | 1076-5174 |
| 其他题名 | 气相中的苯正离子参与的亲电芳香族取代及单电子转移——单电子转移中间体研 |
| 通讯作者 | 郭寅龙 |
| 英文摘要 | Gas-phase mass spectrometric studies and calculations were performed for the reaction of naked phenylium ion with several benzene halides. From these reactions, the molecular ion for biphenyl as the predominant product was obtained only from the reaction of phenylium ions with iodobenzene and bromobenzene. Furthermore, through the collision-induced dissociation (CID) of the ion at m/z 281, the only dissociation observed is the loss of a phenyl radical, which indicates that a single-electron transfer (SET) mechanism might have occurred within the reaction. Additionally, according to the comparison between the CID experiments of those isomeric compounds of the a-complexes and the CID experiment of the ion at m/z 281 captured in the ion trap, we have also defined the captured ion at m/z 281 as an SET-intimate ion pair rather than those of a-complexes or the diphenyliodonium. Copyright (c) 2008 John Wiley & Sons, Ltd. |
| 学科主题 | 分析化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1002/jms.1467 |
| 语种 | 英语 |
| WOS记录号 | WOS:000262917100005 |
| 公开日期 | 2013-02-25 |
| 源URL | [http://202.127.28.38/handle/331003/19994]  |
| 专题 | 上海有机化学研究所_分析化学研究室 |
| 推荐引用方式 GB/T 7714 | Yao SJ,Zhang X,Zhou J,et al. Electrophilic aromatic substitution and single-electron transfer (SET) by the phenylium ion in the gas phase: characterization of a long-lived SET intermediate[J]. J. Mass Spectrom.,2009,44(1):32-39. |
| APA | 姚胜军.,张祥.,周静.,钱荣.,许哲.,...&郭寅龙.(2009).Electrophilic aromatic substitution and single-electron transfer (SET) by the phenylium ion in the gas phase: characterization of a long-lived SET intermediate.J. Mass Spectrom.,44(1),32-39. |
| MLA | 姚胜军,et al."Electrophilic aromatic substitution and single-electron transfer (SET) by the phenylium ion in the gas phase: characterization of a long-lived SET intermediate".J. Mass Spectrom. 44.1(2009):32-39. |
入库方式： OAI收割
来源：上海有机化学研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。