Studies of the Interesting Gas-phase Rearrangement Reactions of 2-Pyrimidinyloxy-N-arylbenzylurea Promoted by Urea-Carbamimidic Acid Tautomerism by ESI-MS/MS and Theoretical Computation
文献类型:期刊论文
| 作者 | Xu C(许楚) ; Wang HY(王昊阳) ; Zhao ZX(赵志雄) ; Tang QH(唐庆红) ; Guo YL(郭寅龙) ; Lv L(吕龙) |
| 刊名 | Chin. J. Chem.
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| 出版日期 | 2010 |
| 卷号 | 28期号:9页码:1765-1772 |
| ISSN号 | 1001-604X |
| 其他题名 | ESI-MS/MS结合理论计算研究有趣的 Urea-Carbamimidic Acid Tautomerism引起的 2-Pyrimidinyloxy-N-arylbenzylurea气相重排反应 |
| 通讯作者 | 郭寅龙 ; 吕龙 |
| 英文摘要 | The gas-phase rearrangement reactions of compound 1, 2-dimethoxypyrimidinyloxybenzylaminobenzenedipropylurea, were studied by ESI-MS/MS. The experimental results showed that introduction of dipropylurea moiety into the molecule initiated various interesting gas-phase chemistries and the mechanisms were proposed on the basis of hydrogen/deuterium (H/D) exchange experiments and theoretical computations. Moreover, product 2, the solution-phase rearrangement product of compound 1, was synthesized and its gas-phase chemistries were also studied to support the propos gas-phase rearrangement reactions of compound 1. |
| 学科主题 | 分析化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1002/cjoc.201090298 |
| 语种 | 英语 |
| WOS记录号 | WOS:000282998700041 |
| 公开日期 | 2013-02-25 |
| 源URL | [http://202.127.28.38/handle/331003/20006] ![]() |
| 专题 | 上海有机化学研究所_分析化学研究室 |
| 推荐引用方式 GB/T 7714 | Xu C,Wang HY,Zhao ZX,et al. Studies of the Interesting Gas-phase Rearrangement Reactions of 2-Pyrimidinyloxy-N-arylbenzylurea Promoted by Urea-Carbamimidic Acid Tautomerism by ESI-MS/MS and Theoretical Computation[J]. Chin. J. Chem.,2010,28(9):1765-1772. |
| APA | 许楚,王昊阳,赵志雄,唐庆红,郭寅龙,&吕龙.(2010).Studies of the Interesting Gas-phase Rearrangement Reactions of 2-Pyrimidinyloxy-N-arylbenzylurea Promoted by Urea-Carbamimidic Acid Tautomerism by ESI-MS/MS and Theoretical Computation.Chin. J. Chem.,28(9),1765-1772. |
| MLA | 许楚,et al."Studies of the Interesting Gas-phase Rearrangement Reactions of 2-Pyrimidinyloxy-N-arylbenzylurea Promoted by Urea-Carbamimidic Acid Tautomerism by ESI-MS/MS and Theoretical Computation".Chin. J. Chem. 28.9(2010):1765-1772. |
入库方式: OAI收割
来源:上海有机化学研究所
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