An Organocatalytic Asymmetric Tandem Reaction for the Construction of Bicyclic Skeletons
文献类型：期刊论文
| 作者 | Cao CL(曹春利) ; Zhou YY(周友运) ; Zhou J(周剑) ; Sun XL(孙秀丽) ; Tang Y(唐勇) ; Li YX(李玉学) ; Li GY(李光玉) ; Sun J(孙杰) |
| 刊名 | Chem.-Eur. J.
 |
| 出版日期 | 2009 |
| 卷号 | 15期号:42页码:11384-11389 |
| ISSN号 | 0947-6539 |
| 其他题名 | An Organocatalytic Asymmetric Tandem Reaction for the Construction of Bicyclic Skeletons |
| 通讯作者 | 唐勇 ; 李玉学 |
| 英文摘要 | Cyclic ketones react with (E)-2-nitroallylic acetates in the presence of catalytic pyrrolidine-thiourea, which affords bicyclic skeletons with four or five stereocenters in one single reaction with up to 98% ee in moderate to high yields. The cooperative effects of both enamine and the Bronsted acid are found to be crucial for the high reactivity and enantioselectivity of this cascade reaction, which is demonstrated by both theoretical calculation and experimental data. |
| 学科主题 | 金属有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1002/chem.200900696 |
| 语种 | 英语 |
| WOS记录号 | WOS:000271560000039 |
| 公开日期 | 2013-02-25 |
| 源URL | [http://202.127.28.38/handle/331003/19357]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Cao CL,Zhou YY,Zhou J,et al. An Organocatalytic Asymmetric Tandem Reaction for the Construction of Bicyclic Skeletons[J]. Chem.-Eur. J.,2009,15(42):11384-11389. |
| APA | 曹春利.,周友运.,周剑.,孙秀丽.,唐勇.,...&孙杰.(2009).An Organocatalytic Asymmetric Tandem Reaction for the Construction of Bicyclic Skeletons.Chem.-Eur. J.,15(42),11384-11389. |
| MLA | 曹春利,et al."An Organocatalytic Asymmetric Tandem Reaction for the Construction of Bicyclic Skeletons".Chem.-Eur. J. 15.42(2009):11384-11389. |
入库方式： OAI收割
来源：上海有机化学研究所
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