中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
An Organocatalytic Asymmetric Tandem Reaction for the Construction of Bicyclic Skeletons

文献类型:期刊论文

作者Cao CL(曹春利) ; Zhou YY(周友运) ; Zhou J(周剑) ; Sun XL(孙秀丽) ; Tang Y(唐勇) ; Li YX(李玉学) ; Li GY(李光玉) ; Sun J(孙杰)
刊名Chem.-Eur. J.
出版日期2009
卷号15期号:42页码:11384-11389
ISSN号0947-6539
其他题名An Organocatalytic Asymmetric Tandem Reaction for the Construction of Bicyclic Skeletons
通讯作者唐勇 ; 李玉学
英文摘要Cyclic ketones react with (E)-2-nitroallylic acetates in the presence of catalytic pyrrolidine-thiourea, which affords bicyclic skeletons with four or five stereocenters in one single reaction with up to 98% ee in moderate to high yields. The cooperative effects of both enamine and the Bronsted acid are found to be crucial for the high reactivity and enantioselectivity of this cascade reaction, which is demonstrated by both theoretical calculation and experimental data.
学科主题金属有机化学
收录类别SCI
原文出处http://dx.doi.org/10.1002/chem.200900696
语种英语
WOS记录号WOS:000271560000039
公开日期2013-02-25
源URL[http://202.127.28.38/handle/331003/19357]  
专题上海有机化学研究所_金属有机化学国家重点实验室
推荐引用方式
GB/T 7714
Cao CL,Zhou YY,Zhou J,et al. An Organocatalytic Asymmetric Tandem Reaction for the Construction of Bicyclic Skeletons[J]. Chem.-Eur. J.,2009,15(42):11384-11389.
APA 曹春利.,周友运.,周剑.,孙秀丽.,唐勇.,...&孙杰.(2009).An Organocatalytic Asymmetric Tandem Reaction for the Construction of Bicyclic Skeletons.Chem.-Eur. J.,15(42),11384-11389.
MLA 曹春利,et al."An Organocatalytic Asymmetric Tandem Reaction for the Construction of Bicyclic Skeletons".Chem.-Eur. J. 15.42(2009):11384-11389.

入库方式: OAI收割

来源:上海有机化学研究所

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