Reaction of Allylic Phosphoranes with Iron Porphyrin Carbenoids: Efficient, Selective, and Catalytic Intermolecular Formal Carbenoid Insertion into Olefinic C-H Bonds
文献类型：期刊论文
| 作者 | Wang RX(汪日新) ; Zhu CY(朱纯银) ; Sun XL(孙秀丽) ; Tang Y(唐勇) |
| 刊名 | J. Am. Chem. Soc.
 |
| 出版日期 | 2009 |
| 卷号 | 131期号:12页码:4192-4193 |
| ISSN号 | 0002-7863 |
| 其他题名 | Reaction of Allylic Phosphoranes with Iron Porphyrin Carbenoids: Efficient, Selective, and Catalytic Intermolecular Formal Carbenoid Insertion into Olefinic C-H Bonds |
| 通讯作者 | 唐勇 |
| 英文摘要 | A highly efficient, selective, and catalytic intermolecular formal carbenoid insertion reaction into olefinic C-H bonds of allylic phosphoranes is described. This novel insertion reaction proved to proceed via a catalytic cyclopropanation of allylic phosphoranes with diazoacetate, followed by ring opening of the resulting cyclopropane ylide. On the basis of this observation, a facile synthetic method yielding 1,1,4-trisubstituted 1,3-butadienes with high stereoselectivity by a one-pot reaction of tributylphosphine-derived salt 11 with MDA and aldehydes under mild conditions has been developed. |
| 学科主题 | 金属有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1021/ja8097959 |
| 语种 | 英语 |
| WOS记录号 | WOS:000264792900011 |
| 公开日期 | 2013-02-25 |
| 源URL | [http://202.127.28.38/handle/331003/19373]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Wang RX,Zhu CY,Sun XL,et al. Reaction of Allylic Phosphoranes with Iron Porphyrin Carbenoids: Efficient, Selective, and Catalytic Intermolecular Formal Carbenoid Insertion into Olefinic C-H Bonds[J]. J. Am. Chem. Soc.,2009,131(12):4192-4193. |
| APA | 汪日新,朱纯银,孙秀丽,&唐勇.(2009).Reaction of Allylic Phosphoranes with Iron Porphyrin Carbenoids: Efficient, Selective, and Catalytic Intermolecular Formal Carbenoid Insertion into Olefinic C-H Bonds.J. Am. Chem. Soc.,131(12),4192-4193. |
| MLA | 汪日新,et al."Reaction of Allylic Phosphoranes with Iron Porphyrin Carbenoids: Efficient, Selective, and Catalytic Intermolecular Formal Carbenoid Insertion into Olefinic C-H Bonds".J. Am. Chem. Soc. 131.12(2009):4192-4193. |
入库方式： OAI收割
来源：上海有机化学研究所
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