Synthesis of perfluoroalkylated sugars catalyzed by rabbit muscle aldolase (RAMA)
文献类型：期刊论文
| 作者 | Zhu W(朱伟) ; Li ZY(李祖义) |
| 刊名 | J. Chem. Soc.-Perkin Trans. 1
 |
| 出版日期 | 2000 |
| 期号 | 7页码:1105-1108 |
| ISSN号 | 1472-7781 |
| 其他题名 | 兔肌醛缩酶(RAMA)催化合成全氟碳链糖类化合物 |
| 通讯作者 | 李祖义 |
| 英文摘要 | Perfluoroalkyl iodides [RfI: Cl(CF^2)^4I, Cl(CF^2)^6I, C^8F^17I] react with acrolein diethyl acetal catalyzed by sulfinatodehalogenation reagents to produce 2-iodo-3-(perfluoroalkyl)propanal diethyl acetal 1, which is converted into (E)-3-(perfluoroalkyl)acrolein diethyl acetals 2 on treatment by base (KOH-MeOH). 3-perfluoroalkyl-D-glyceraldhyde diethyl acetals 3 are produced through the asymmetric dihydroxylation (AD) of compound 2. Then 3 are easily hydrolyzed to 3-perfluoroalkyl-D-glyceraldehydes 4, which could react with DHAP catalyzed by RAMA and further acid phosphatase to form 6-C-perfluoroalkyl-D-fructose, which is a novel sugar and surfactant. |
| 学科主题 | 生命有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1039/a910336h |
| 语种 | 英语 |
| WOS记录号 | WOS:000086164800006 |
| 公开日期 | 2013-02-25 |
| 源URL | [http://202.127.28.38/handle/331003/19683]  |
| 专题 | 上海有机化学研究所_金属有机化学国家重点实验室 |
| 推荐引用方式 GB/T 7714 | Zhu W,Li ZY. Synthesis of perfluoroalkylated sugars catalyzed by rabbit muscle aldolase (RAMA)[J]. J. Chem. Soc.-Perkin Trans. 1,2000(7):1105-1108. |
| APA | 朱伟,&李祖义.(2000).Synthesis of perfluoroalkylated sugars catalyzed by rabbit muscle aldolase (RAMA).J. Chem. Soc.-Perkin Trans. 1(7),1105-1108. |
| MLA | 朱伟,et al."Synthesis of perfluoroalkylated sugars catalyzed by rabbit muscle aldolase (RAMA)".J. Chem. Soc.-Perkin Trans. 1 .7(2000):1105-1108. |
入库方式： OAI收割
来源：上海有机化学研究所
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