"Ligand-Free" CuI-Catalyzed Highly Efficient Intramolecular S-Vinylation of Thiols with Vinyl Chlorides and Bromides
文献类型：期刊论文
| 作者 | Zhao QW(赵启武) ; Li L(李凌) ; Fang YW(方烨汶) ; Sun DQ(孙德谦) ; Li CZ(李超忠) |
| 刊名 | J. Org. Chem.
 |
| 出版日期 | 2009 |
| 卷号 | 74期号:1页码:459-462 |
| ISSN号 | 0022-3263 |
| 其他题名 | “无配体”碘化亚铜催化的硫醇与烯基氯、溴化物的高效分子内S－烯基化反应 |
| 通讯作者 | 李超忠 |
| 英文摘要 | With CuI as the catalyst and K3PO4 center dot 3H(2)O as the base, highly efficient intramolecular S-vinylation of thiols with vinyl chlorides or bromides was successfully implemented without the help of an additional ligand. Moreover, the competition experiments revealed that the 4-exo cyclization is fundamentally preferred over other modes (5-exo, 6-exo, and 6-endo) of cyclization. |
| 学科主题 | 金属有机化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1021/jo802235e |
| 语种 | 英语 |
| WOS记录号 | WOS:000262004000063 |
| 公开日期 | 2013-03-04 |
| 源URL | [http://202.127.28.38/handle/331003/22856]  |
| 专题 | 上海有机化学研究所_中科院天然产物有机化学重点实验室 |
| 推荐引用方式 GB/T 7714 | Zhao QW,Li L,Fang YW,et al. "Ligand-Free" CuI-Catalyzed Highly Efficient Intramolecular S-Vinylation of Thiols with Vinyl Chlorides and Bromides[J]. J. Org. Chem.,2009,74(1):459-462. |
| APA | 赵启武,李凌,方烨汶,孙德谦,&李超忠.(2009)."Ligand-Free" CuI-Catalyzed Highly Efficient Intramolecular S-Vinylation of Thiols with Vinyl Chlorides and Bromides.J. Org. Chem.,74(1),459-462. |
| MLA | 赵启武,et al.""Ligand-Free" CuI-Catalyzed Highly Efficient Intramolecular S-Vinylation of Thiols with Vinyl Chlorides and Bromides".J. Org. Chem. 74.1(2009):459-462. |
入库方式： OAI收割
来源：上海有机化学研究所
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