The fragmentation reaction of 16R-bromopregnane-3S,20S-diol
文献类型:期刊论文
作者 | Lin JR(林静容) ; Zhou NY(周南琰) ; Jiang SF(蒋世风) ; Xu QH(许启海) ; Tian WS(田伟生) |
刊名 | Tetrahedron Lett.
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出版日期 | 2007 |
卷号 | 48期号:29页码:4987-4989 |
ISSN号 | 0040-4039 |
其他题名 | 16R-溴代孕甾-3 S, 20S-二醇的碎裂反应 |
通讯作者 | 田伟生 |
英文摘要 | 16R-Bromopregnane-3S,20S-diol reacted with potassium t-butoxide to afford androst-16-en-3S-ol in a moderate yield via fragmentation reaction. The latter is a key intermediate for the synthesis of 5 alpha-androst-16-en-3-one, as boar sex pheromone, and other steroidal drugs. In addition, 16R,20S-epoxypregnane-3S-ol was also obtained as a major product by changing the reaction solvent. (C) 2007 Elsevier Ltd. All rights reserved. |
学科主题 | 天然产物有机化学 |
收录类别 | SCI |
原文出处 | http://dx.doi.org/10.1016/j.tetlet.2007.05.126 |
语种 | 英语 |
WOS记录号 | WOS:000247995900006 |
公开日期 | 2013-03-11 |
源URL | [http://202.127.28.38/handle/331003/23858] ![]() |
专题 | 上海有机化学研究所_中科院天然产物有机化学重点实验室 |
推荐引用方式 GB/T 7714 | Lin JR,Zhou NY,Jiang SF,et al. The fragmentation reaction of 16R-bromopregnane-3S,20S-diol[J]. Tetrahedron Lett.,2007,48(29):4987-4989. |
APA | 林静容,周南琰,蒋世风,许启海,&田伟生.(2007).The fragmentation reaction of 16R-bromopregnane-3S,20S-diol.Tetrahedron Lett.,48(29),4987-4989. |
MLA | 林静容,et al."The fragmentation reaction of 16R-bromopregnane-3S,20S-diol".Tetrahedron Lett. 48.29(2007):4987-4989. |
入库方式: OAI收割
来源:上海有机化学研究所
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