Radical (phenylsulfonyl)difluoromethylation with iododifluoromethyl phenyl sulfone
文献类型：期刊论文
| 作者 | Li Y(李亚) ; Liu J(刘俊) ; Zhang LJ(张来俊) ; Zhu LG(朱林桂) ; Hu JB(胡金波) |
| 刊名 | J. Org. Chem.
 |
| 出版日期 | 2007 |
| 卷号 | 72期号:15页码:5824-5827 |
| ISSN号 | 0022-3263 |
| 其他题名 | 利用一碘二氟甲基苯基砜进行自由基苯磺酰二氟甲基化反应 |
| 通讯作者 | 胡金波 |
| 英文摘要 | An unprecedented radical (phenylsulfonyl)difluoromethylation of terminal alkenes with PhSO2CF2I has been achieved by using Et3B/air as an initiator. This synthetic methodology was also used in the one-pot regioselective preparation of PhSO2CF2-substituted alkanes, and in the regio- and stereoselective preparation of PhSO2CF2-substituted alkenes with high E/Z ratio (up to >= 100:1). |
| 学科主题 | 氟化学 |
| 收录类别 | SCI |
| 原文出处 | http://dx.doi.org/10.1021/jo070618s |
| 语种 | 英语 |
| WOS记录号 | WOS:000247992800046 |
| 公开日期 | 2013-03-11 |
| 源URL | [http://202.127.28.38/handle/331003/24017]  |
| 专题 | 上海有机化学研究所_中科院有机氟化学重点实验室 |
| 推荐引用方式 GB/T 7714 | Li Y,Liu J,Zhang LJ,et al. Radical (phenylsulfonyl)difluoromethylation with iododifluoromethyl phenyl sulfone[J]. J. Org. Chem.,2007,72(15):5824-5827. |
| APA | 李亚,刘俊,张来俊,朱林桂,&胡金波.(2007).Radical (phenylsulfonyl)difluoromethylation with iododifluoromethyl phenyl sulfone.J. Org. Chem.,72(15),5824-5827. |
| MLA | 李亚,et al."Radical (phenylsulfonyl)difluoromethylation with iododifluoromethyl phenyl sulfone".J. Org. Chem. 72.15(2007):5824-5827. |
入库方式： OAI收割
来源：上海有机化学研究所
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